화학공학소재연구정보센터
Materials Chemistry and Physics, Vol.136, No.2-3, 296-299, 2012
Complex atomic dynamics in a deep-eutectic binary metallic melt
Quasielastic neutron scattering (QENS) was used to explore relaxation processes in a deep-eutectic Ce80Ni20 melt over a temperature range of 750 K, i.e., from 775 K to 1525 K. At low temperatures (T <= 890 K), the self-correlation function shows a fast beta-relaxation process. The alpha-relaxation process displays stretching of the self-correlation and obeys a time temperature superposition principle that extends over the entire measured temperature range. Even though the decay of the self-correlation functions of the Ce80Ni20 melt exhibit that of glass-forming melts, the temperature dependence of self-diffusivity displays an Arrhenius behavior, as observed for many simple, non-glass forming liquids. Published by Elsevier B.V.