The role of fuel/oxidizer ratio in the synthesis conditions of Cu-Al2O3 nanocomposite, which was prepared through solution combustion synthesis, method was investigated. For this purpose, copper and aluminum nitrates as well as urea were used as oxidizer and fuel, respectively. The fuel/oxidizer (F/O) ratios were selected from the range of 0.9-1.75. The products were analyzed using X-ray diffraction, SEM and TEM techniques. During the process the temperature was recorded as a function of time. The results showed that by increasing the F/O ratio up to the stoichiometric amount, the combustion temperature increases. Further increment of F/O ratio resulted in a decrease in the combustion temperature. Microscopic evaluations, using SEM and TEM, proved feasibility of the production of Cu-Al2O3 through this method. (C) 2012 Elsevier Ltd. All rights reserved.