화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.30, No.3, 714-723, March, 2013
DOI10.1007/s11814-012-0194-x  Export Citation
Adsorption of phenol and 1-naphthol onto XC-72 carbon
Liming Zuo, Shaoming Yu†, Leilei Cheng, and Erling Du
  • School of Chemical Engineering, Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, Hefei University of Technology, Hefei 230009, Anhui, China
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XC-72 carbon (XC-72) was characterized by SEM, XPS, N2 adsorption-desorption, particle size distribution analysis and potentiometric acid-base titration. The adsorption of phenol and 1-naphthol on XC-72 was studied as a function of contact time, pH, adsorbent content and temperature. The kinetic adsorption data were described well by the pseudo-second-order model. The adsorption isotherms of phenol were described well by Freundlich model, while the adsorption isotherms of 1-naphthol were fitted well by Langmuir model. The results demonstrated that XC-72 had much higher adsorption capacity for 1-naphthol than for phenol. The adsorption thermodynamic data were calculated from the temperature-dependent adsorption isotherms at T=293, 313 and 333 K, and the results indicated that the adsorption of phenol was an exothermic process, whereas the adsorption of 1-naphthol was an endothermic process. XC-72 is a suitable material for the preconcentration of phenol and 1-naphthol from large volumes of aqueous solutions.
Keywords:XC-72 Carbon;Adsorption;Phenol;1-Naphthol;Kinetics
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