Separation of nickel(II) and cadmium(II) ions from sulphate solution has been studied. The solutions of Ni(II) and Cd(II) have been treated with different exchange resins: Lewatit OC-1026, Lewatit TP-207, and Lewatit MonoPlus SP 112. Data obtained from the ion-exchange process was compared with data from the supported liquid membrane experiment. It was shown that the use of the supported liquid membrane process enables separation of investigated ions. In this process the highest recovery factor was obtained. The best separation of metal ions was obtained for the ion-exchange process with Lewatit OC 1026.