화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.3, 854-862, May, 2013
DOI10.1016/j.jiec.2012.10.031  Export Citation
Preparation and characterization of PVC based heterogeneous ion exchange membrane coated with Ag nanoparticles by (thermal-plasma) treatment assisted surface modification
S.M. Hosseini†, S.S. Madaeni1, A. Zendehnam2, A.R. Moghadassi, A.R. Khodabakhshi3, and H. Sanaeepur
  • Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran
  • 1Membrane Research Centre, Department of Chemical Engineering, Faculty of Engineering, Razi University, Kermanshah 67149, Iran
  • 2Thin film laboratory, Department of physic, Faculty of Science, Arak University, Arak 38156-8-8349, Iran
  • 3Department of chemistry, Faculty of Science, Arak University, Arak 38156-8-8349, Iran
E-mail:
PVC based heterogeneous cation exchange membranes were prepared by solution casting technique. Ag nanoparticles were also utilized as surface modifier by plasma treatment. Thermal treatment was used to improve the Ag nanoparticles stability on membrane surface. The effect of treating temperature on separation characteristics of coated membranes was studied. SEM images showed membrane rugosity increasing by the increase of treating temperature. Transport number, selectivity and permeability were enhanced initially by increase of treating temperature up to 80 ℃ and then showed decreasing trend. Conversely membrane resistance showed opposite trend. Modified membrane at 80 8C showed better performance compared to others.
Keywords:Thermal/Plasma treatment;Surface modification;Ag nanoparticles;Electrochemical characterization
  1. Hosseini SM, Madaeni SS, Khodabakhshi AR, Zendehnam A, J. Membr. Sci., 365(1-2), 438 (2010)
  2. Hosseini SM, Madaeni SS, Khodabakhshi AR, J. Membr. Sci., 351(1-2), 178 (2010)
  3. Hosseini SM, Madaeni SS, Khodabakhshi AR, J. Membr. Sci., 362(1-2), 550 (2010)
  4. Hosseini SM, Madaeni SS, Khodabakhshi AR, Sep. Sci. Technol., 45(16), 2308 (2010)
  5. Hosseini SM, Madaeni SS, Khodabakhshi AR, Sep. Sci. Technol., 46(5), 794 (2011)
  6. Hosseini SM, Madaeni SS, Khodabakhshi AR, J. Appl. Polym. Sci., 118(6), 3371 (2010)
  7. Nagarale RK, Gohil GS, Shahi VK, Trivedi GS, Rangarajan R, J. Colloid Interface Sci., 277(1), 162 (2004)
  8. Vyas PV, Ray P, Adhikary SK, Shah BG, Rangarajan R, J. Colloid Interface Sci., 257(1), 127 (2003)
  9. Kariduraganavar MY, Nagarale RK, Kittur AA, Kulkarni SS, Desalination, 197(1-3), 225 (2006)
  10. Nagarale RK, Shahi VK, Schubert R, Rangarajan R, Mehnert R, J. Colloid Interface Sci., 270(2), 446 (2004)
  11. Hwang GJ, Ohya H, Nagai T, J. Membr. Sci., 156(1), 61 (1999)
  12. M'Bareck CO, Nguyen QT, Alexandre S, Zimmerlin I, J. Membr. Sci., 278(1-2), 10 (2006)
  13. Xu TW, J. Membr. Sci., 263(1-2), 1 (2005)
  14. Elattar A, Elmidaoui A, Pismenskaia N, Gavach C, Pourcelly G, J. Membr. Sci., 143(1-2), 249 (1998)
  15. Schauer J, Brozova L, J. Membr. Sci., 250(1-2), 151 (2005)
  16. Baker RW, Membrane Technology and Applications, 2nd edition, John Wiley & Sons Ltd., England (2004)
  17. Koter S, Warszawski A, Polish Journal of Environmental Studies., 9(1), 45 (2000)
  18. Shahi VK, Trivedi GS, Thampy SK, Rangarajan R, J. Colloid Interface Sci., 262(2), 566 (2003)
  19. Dlugolecki P, Anet B, Metz SJ, Nijmeijer K, Wessling M, J. Membr. Sci., 346(1), 163 (2010)
  20. Gohil GS, Shahi VK, Rangarajan R, J. Membr. Sci., 240(1-2), 211 (2004)
  21. Nagarale RK, Shahi VK, Thampy SK, Rangarajan R, Reactive & Functional Polymers., 61, 131 (2004)
  22. Nagarale RK, Gohil GS, Shahi VK, Advanced in Colloid and Interface Science., 119, 97 (2006)
  23. Kerres J, Cui W, Disson R, Neubrand W, J. Membr. Sci., 139(2), 211 (1998)
  24. Li XF, Wang Z, Lu H, Zhao CJ, Na H, Zhao C, J. Membr. Sci., 254(1-2), 147 (2005)
  25. Sata T Ion Exchange Membranes: Preparation, Characterization, Modification and Application, The Royal Society of Chemistry, Cambridge, United Kingdom (2004)
  26. Kiyono R, Koops GH, Wessling M, Strathmann H, J. Membr. Sci., 231(1-2), 109 (2004)
  27. Wiks ES, Industrial Polymers Handbook: Products, Processes Application, WILEY-VCH Press, Germany (2001)
  28. James E, MARK Polymer Data Handbook, Oxford University Press, Inc., New York (1999)
  29. Harper CA, Handbook of Plastic and Elastomers, McGraw-Hill, New York (1975)
  30. Ma N, Fan XF, Quan X, Zhang YB, J. Membr. Sci., 336(1-2), 109 (2009)
  31. Duran N, Marcato PD, De Souza GIH, Alves OL, Esposito E, Journal of Biomedical Nanotechnology., 3, 203 (2007)
  32. Lv YH, Liu H, Wang Z, Liu SJ, Hao LJ, Sang YH, Liu D, Wang JY, Boughton RI, J. Membr. Sci., 331(1-2), 50 (2009)
  33. Rahimpour A, Madaeni SS, Amirinejad M, Mansourplanah Y, Zereshki S, J. Membr. Sci., 330(1-2), 189 (2009)
  34. Mansourpanah Y, Madaeni SS, Rahimpour A, Farhadian A, Appl. Surf. Sci., 255(20), 8395 (2009)
  35. Powell CE, Qiao GG, J. Membr. Sci., 279(1-2), 1 (2006)
  36. Shahi VK, Thampy SK, Rangarajan R, J. Membr. Sci., 158(1-2), 77 (1999)
  37. Nagarale RK, Gohil GS, Shahi VK, Rangarajan R, Colloids and Surfaces A: Physicochemical and Engineering Aspects., 251, 133 (2004)
  38. Tanaka Y, Ion Exchange Membranes: Fundamentals and Applications, Membrane Science and Technology Series, 12, Elsevier, Netherlands (2007)
  39. Gohil GS, Binsu VV, Shahi VK, J. Membr. Sci., 280(1-2), 210 (2006)
  40. Schauer J, Kudela V, Richau K, Mohr R, Desalination, 198(1-3), 256 (2006)
  41. Lide DR, CRC Handbook of Chemistry and Physics, 87th edition, CRC Press, 2006-2007
  42. Kang MS, Choi YJ, Choi IJ, Yoon TH, Moon SH, J. Membr. Sci., 216(1-2), 39 (2003)
  43. Dlugolecki P, Nymeijer K, Metz S, Wessling M, J. Membr. Sci., 319(1-2), 214 (2008)