Heavy toxic metal ion exchange kinetics: Validation of ion exchange process on composite cation exchanger nylon 6,6 Zr(IV) phosphate

Zeid A. AlOthman; Mohammad Mezbaul Alam; Mu. Naushad

Journal of Industrial and Engineering Chemistry, Vol.19, No.3, 956-960, May, 2013

DOI10.1016/j.jiec.2012.11.016 Export Citation

Heavy toxic metal ion exchange kinetics: Validation of ion exchange process on composite cation exchanger nylon 6,6 Zr(IV) phosphate

Zeid A. AlOthman, Mohammad Mezbaul Alam^†, and Mu. Naushad

Advanced Materials Research Chair, Department of Chemistry, College of Science, King Saud University, Building 5, Riyadh, Saudi Arabia

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Nernst-Planck equation was applied to study the heavy metal ion exchange kinetics over the surface of nylon 6,6 Zr(IV) phosphate at various temperatures under particle diffusion controlled phenomena. Various useful ion exchange kinetic parameters such as self-diffusion coefficient (Do), energy of activation (Ea), and entropy of activation (△S*) were evaluated to validate the ion exchange process for practical applicability of this composite cation exchanger in remediation processes of the environment. This study is also supported for the good selectivity of Cu(II) to validate the practical application of this cation exchanger in environmental analysis.

Keywords:Organic-inorganic composite;Cation exchanger;Nylon 6,6 Zr(IV) phosphate;Ion exchange kinetics

[References]

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[Referenced By]

[1] Idris A, Ismail NSM, Hassan N, Misran E, Ngomsik AF, J. Ind. Eng. Chem., 18(5), 1582 (2012)

[2] Badruddoz AZM, Shawon ZBZ, Daniel TWJ, Hidajat K, Shahabuddin M, Carbohydrate Polymers., 91, 322 (2013)

[3] Zhu JH, Wei SY, Gu HB, Rapole SB, Wang Q, Luo ZP, Haldolaarachchige N, Young DP, Guo ZH, Environmental Science and Technology., 46, 977 (2012)

[4] Liu JS, Ma Y, Xu TW, Shao GQ, J. Hazard. Mater., 178(1-3), 1021 (2010)

[5] Vinodh R, Padmavathi R, Sangeetha D, Desalination, 267(2-3), 267 (2011)

[6] Camci-Unal G, Pohl NLB, J. Chem. Eng. Data, 55(3), 1117 (2010)

[7] Kiefer R, Holl WH, Ind. Eng. Chem. Res., 40(21), 4570 (2001)

[8] Guclu G, Gurdag G, Ozgumus S, J. Appl. Polym. Sci., 90(8), 2034 (2003)

[9] Al-Othman ZA, Naushad M, Inamuddin, Chem. Eng. J., 172(1), 369 (2011)

[10] Gupta VK, Suhas, Journal of Environment Management., 90, 2313 (2009)

[11] Xu M, Zhang YS, Zhang ZM, Shen Y, Zhao MJ, Pan GT, Chem. Eng. J., 168(2), 737 (2011)

[12] Cesur H, Balkaya N, Chem. Eng. J., 131(1-3), 203 (2007)

[13] Machida M, Fotoohi B, Amamo Y, Mercier L, Appl. Surf. Sci., 258(19), 7389 (2012)

[14] Clearfield A, Medina AS, Journal of Inorganic and Nuclear Chemistry., 32, 2775 (1970)

[15] Alberti G, Bertrami R, Caseola M, Costantino U, Gupta JP, Journal of Inorganic and Nuclear Chemistry., 38, 843 (1976)

[16] Saraswat IP, Srivastava SK, Sharma AK, Canadian Journal of Chemistry., 57, 1214 (1979)

[17] Singh NJ, Mathew J, Tandon SN, Journal of Physical Chemistry., 84, 21 (1980)

[18] Boyd GE, Adamson AW, Myers LS, Journal of the American Chemical Society., 69, 2836 (1947)

[19] Reichenberg D, Journal of the American Chemical Society., 75, 589 (1953)

[20] Helfferich F, Ion Exchange, McGraw-Hill, New York, (Chapter 6). (1962)

[21] Nernst W, Zeitschrift fur Physikalische Chemie., 4, 129 (1889)

[22] Planck M, Annalen der Physik und Chemie., 39, 161 (1890)

[23] Inamuddin, Khan SA, Siddiqui WA, Khan AA, Talanta., 71, 841 (2007)

[24] Reilley CN, Schmidt RW, Sadek FS, Journal of Chemical Education., 36, 555 (1959)

[25] Kodama S, Fukui K, Mazume A, Industrial and Engineering Chemistry., 45, 1644 (1953)

[26] Helfferich F, Plesset MS, Journal of Chemical Physics., 28, 418 (1958)

[27] Plesset MS, Helfferich F, Franklin JN, Journal of Chemical Physics., 29, 1064 (1958)