화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.30, No.6, 1265-1271, June, 2013
Fabrication and modification of polyvinylchloride based heterogeneous cation exchange membranes by simultaneously using Fe-Ni oxide nanoparticles and Ag nanolayer: Physico-chemical and antibacterial characteristics
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Polyvinylchloride-blend-styrene butadiene rubber based nanocomposite cation exchange membranes were prepared by solution casting technique. Iron-oxide nanoparticles and Ag-nanolayer were simultaneously utilized as filler and surface modifier in membrane fabrication. The effects of Ag-nanolayer film thickness on membrane physicochemical and antibacterial characteristics of nanocomposite PVC-blend-SBR/Iron-oxide nanoparticles were studied. SEM images showed membrane roughness decreasing by Ag nanolayer thickness increasing. Membrane charge density and selectivity declined by Ag nanolayer coating up to 5 nm in membranes and then showed increasing trend by more nanolayer thickness. Ionic flux also showed increasing trend. Membranes showed good ability in E-Coli removal. 20 nm Ag-nanolayer coated membrane showed better performance compared to others.
  1. Baker RW, Membrane technology and applications, 2nd Ed. Wiley Ltd., England (2004)
  2. Hosseini SM, Madaeni SS, Heidari AR, Moghadassi AR, Desalination, 279(1-3), 306 (2011)
  3. Hideo K, Tsuzura K, Shimizu H, Ion exchange membranes, in: Dorfner K (Ed.), Ion Exchangers, Walter de Gruyter, Berlin (1991)
  4. Strathmann H, Electrodialysis and related processes, in: Nobe RD, Stern SA (Eds.), Membrane Separation Technology-Principles and Applications, Elsevier Science, 214 (1995)
  5. Sata T, Sata T, Yang WK, J. Membr. Sci., 206(1-2), 31 (2002)
  6. Kubuchi Y, Motomura H, Noma Y, Hanada F, J. Membr. Sci., 27, 173 (1986)
  7. Sata T, New application of ion-exchange membranes, in: J. Kohovec (Ed.), Macromolecules, VSP, Utrecht, The Netherlands, 451 (1992)
  8. Gohil GS, Binsu VV, Shahi VK, J. Membr. Sci., 280(1-2), 210 (2006)
  9. Vyas PV, Ray P, Adhikary SK, Shah BG, Rangarajan R, J. Colloid Interface Sci., 257(1), 127 (2003)
  10. Hosseini SM, Madaeni SS, Khodabakhshi AR, J. Appl. Polym. Sci., 118(6), 3371 (2010)
  11. Hosseini SM, Madaeni SS, Heidari AR, Amirimehr A, Desalination., 284, 191 (2012)
  12. Shahi VK, Thampy SK, Rangarajan R, J. Membr. Sci., 158(1-2), 77 (1999)
  13. Kerres J, Cui W, Disson R, Neubrand W, J. Membr. Sci., 139(2), 211 (1998)
  14. Pourjafar S, Rahimpour A, Rahimpour M, J. Ind. Eng. Chem., 18(4), 1398 (2012)
  15. Liu ZM, Xu ZK, Wan LS, Wu J, Ulbricht M, J. Membr. Sci., 249(1-2), 21 (2005)
  16. Yan MG, Liu LQ, Tang ZQ, Huang L, Li W, Zhou J, Gu LS, Wei XW, Yu HY, Chem. Eng. J., 145(2), 218 (2008)
  17. Yu HY, Xie Y, Hu MX, Wang JL, Wang SY, Xu ZK, J. Membr. Sci., 254(1-2), 219 (2005)
  18. Sardohan T, Kir E, Gulec A, Cengeloglu Y, Sep. Purif. Technol., 74(1), 14 (2010)
  19. Hosseini SM, Madaeni SS, Khodabakhshi AR, Zendehnam A, J. Membr. Sci., 365(1-2), 438 (2010)
  20. Wiks ES, Industrial Polymers Handbook: Products, Processes, Application, Wiley-VCH Press, Germany (2001)
  21. Mark JE, Polymer Data Handbook, Oxford University Press, New York (1999)
  22. Harper CA, Handbook of Plastic and Elastomers, McGraw-Hill, New York (1975)
  23. Erertovr L, Physics of Thin Films, Plenum Press, 2nd Ed. (1986)
  24. Chaloupka K, Malam Y, Seifalian AM, Trends Biotechnol., 28, 580 (2010)
  25. Sondi I, Salopek-Sondi B, J. Colloid Interface Sci., 275(1), 177 (2004)
  26. Wei D, Sun W, Qian W, Ye Y, Ma X, Carbohyd. Res., 344, 2375 (2009)
  27. Tang B, Wang JF, Xu SP, Afrin T, Xu WQ, Sun L, Wang XG, J. Colloid Interface Sci., 356(2), 513 (2011)
  28. Li XF, Wang Z, Lu H, Zhao CJ, Na H, Zhao C, J. Membr. Sci., 254(1-2), 147 (2005)
  29. Nagarale RK, Shahi VK, Thampy SK, Rangarajan R, React.Funct. Polym., 61, 131 (2004)
  30. Nagarale RK, Gohil GS, Shahi VK, Rangarajan R, Colloids Surf. A: Physicochemical and Engineering Aspects., 251, 133 (2004)
  31. Lide DR, CRC Handbook of Chemistry and Physics, 87th Ed., CRC press, Boca Raton, FL (2006-2007).