Current Applied Physics, Vol.13, No.4, 743-747, 2013
n-Type microcrystalline silicon oxide layer and its application to high-performance back reflectors in thin-film silicon solar cells
Light trapping is a key issue in improving the efficiency of thin-film Si solar cells, and using a back reflector material plays a critical role in improving a cell's light-trapping efficiency. In this study, we developed n-type microcrystalline silicon oxide (n-mu c-SiOx) films that are suitable for use as back reflectors in thin-film silicon solar cells. They exhibit a lower refractive index and lower absorption spectra, especially at long wavelengths of >700 nm, than conventional ZnO:Al materials, which are beneficial for this application. The n-mu c-SiOx films were prepared by the PECVD (plasma-enhanced chemical vapor deposition) method and applied to the fabrication of back reflectors in mu c-Si:H solar cells. We also characterized the changes in cell performance with respect to the refractive index, conductivity, and thickness of the n-mu c-SiOx back reflectors. The novel back reflector boosts the total current density by up to 3.0% with the help of the enhanced long-wavelength response. It also improves open circuit voltage (V-OC) and fill factor (FF), which may be attributed to the reduced shunt current caused by the anisotropic electrical characteristics of the n-mu c-SiOx layer. Finally, we could achieve a conversion efficiency for the hydrogenated microcrystalline silicon (mu c-Si: H) solar cells of up to 9.3% (V-OC: 0.501 V, J(SC): 27.4 mA/cm(2), FF: 0.68) using the n-mu c-SiOx back reflector. (C) 2012 Elsevier B.V. All rights reserved.
Keywords:n-Type microcrystalline silicon oxide;Thin-film silicon solar cell;Back reflector;Light trapping