Journal of Materials Science, Vol.48, No.11, 4008-4015, 2013
Development of Ni-Fe-Al-based alloys precipitating cubic gamma' for fabrication of nanoporous membranes
During this study, new Ni-base alloys precipitating cubic gamma' were developed which shall be used for the production of polycrystalline nanoporous membranes. The polycrystalline nanoporous membranes are produced through a combination of cold rolling and heat treatment in order to get directional coarsening of the gamma'-phase which is selectively dissolved afterwards. Conventional Ni-based superalloys have a gamma/gamma' -microstructure with cubic gamma'-precipitates and show the needed etching behaviour but their high strength and limited ductility at room temperature do not allow to produce the polycrystalline nanoporous membranes by means of the before mentioned method. Thus, the new alloys with simpler composition were developed which have a gamma/gamma' microstructure. The alloy Ni-13Fe-8Al-4Ti (composition in atomic percent) which was produced by Schmitz (Cullivier, ISBN 978-3-86955-523-2, 16) served as basis and showed the promising characteristics. To obtain cubic gamma'-precipitates, the misfit was estimated to values of at least |0.2| % by a method presented by Mishima (Acta Metall 33:1161-1169, 23). Further, the phase compositions as well as phase volume fractions of gamma-matrix and gamma'-phase were calculated by means of Thermocalc(A (R)) simulations (database: TTNi7). The etching behaviour of the new alloys was adjusted by adding chromium and molybdenum which passivate the gamma-matrix so that the gamma'-precipitates dissolve during the leaching process. The well-aligned cubic gamma'-precipitates were obtained by partially replacing titanium by niobium. Furthermore, the hardness could be significantly lowered compared to conventional superalloys by reduction of alloying elements. Hence, the promising alloys were found to get directional coarsening of the gamma'-precipitates in a combined process of cold rolling and heat treatment.
Keywords:gamma/gamma '-Microstructure;Ni-Fe-Al alloys;Ni3Al;Lattice misfit;Thermodynamic calculation;Etching behaviour