(2,3-Dibromopropyl)Phenyl Octadecanoyl Phosphate 합성과 유연난연제로서의 응용

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Journal of the Korean Industrial and Engineering Chemistry, Vol.3, No.4, 670-677, December, 1992

Export Citation

(2,3-Dibromopropyl)Phenyl Octadecanoyl Phosphate 합성과 유연난연제로서의 응용

Synthesis of(2, 3-Dibromopropyl) Phenyl Octadecanoyl Phospate and Its Application as Softening Flame Retardant

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초록

2, 3-Dibromopropyl alcohol과 chlorophenyl phosphate로 부터 (2, 3-dibromopropyl)phenyl phosphate [DPP]를 합성하고, 또한 DPP에 n-octadecyl chloride를 가하여 (2,3- dibromopropyl)phenyl octadecyl phosphate[DPOP]를 합성하였다. DPP와 DPOP에 각각 유화제를 블렌딩시켜 난연제 DPPF와 DPOPF를 제조하였는데, 모두 o/w(oil in water)유화형 난연제였다. 이 2종류의 난연제를 각종 합성직물에 처리하여 난연성과 인열강도를 측정한 결과 DPPF는 난연성만이, 그리고 DPOPF는 난연성과 유연성 모두 양호하였다.

(2, 3-Dibromopropyl) phenyl phosphate[DPP] was synthesized from 2, 3-dibromopropyl alcohol and chlorophenyl phosphate. Also, (2, 3,-dibromopropyl)phenyl octadecyl phosphate[DPOP] was synthesized from DPP and n-octadecyl chloride. Flame retardants, DPPF and DPOPF, were prepared by blending DPP and DPOP with emulsifier, respectively. The flame retardants prepared were o/w(oil in water) type emulsion flame retardants. As a result of treatments of the flame retardants on various synthetic textiles, DPPF showed only good flame retardancy, but DPOPF showed both good flame retardancy and good softness.

[References]

Textile Flammability and Consumer Safety, Gdi Occasional Publication No. 45, Ruschlikzon-Zurich (1969)
Martin EP, Ciba Rev. (1969)
Sayers LW, Text. Inst. Ind., 3, 168 (1965)
Tessoro GC, Textilveredlung, 1, 208 (1966)
Tolgyesi WS, Krasny JF, Text. Res. J., 37, 298 (1967)
Miles TD, Delasanta AC, Text. Res. J., 38, 273 (1968)
Barker RH, Cell. Chem. Appl., 423 (1985)
Ko SW, Ha WS, J. Korean Fiber Soc., 14, 18 (1977)
Granzow A, Ferrillo RG, Wilson A, J. Appl. Polym. Sci., 21, 1687 (1977)
Avondo G, Vovelle C, Delbourgo R, Combust. Flame, 31, 7 (1978)
Holme L, Patel SR, J.S.D.C., 96, 224 (1980)
Lee ES, Song KG, Ko SW, J. Korean Fiber Soc., 28, 60 (1991)
Lee ES, Song KG, Ko SW, J. Korean Fiber Soc., 28, 66 (1991)
Coover HW, Dickey JB, U.S. Patent, 2,763,631 (1956)
Palethorpe G, U.S. Patent, 3,318,978 (1967)
Park HS, Kim YG, Bea JS, J. Korean Oil Chem. Soc., 7, 31 (1990)
Enders H, Pusch G, Am. Dyest. Rept., 49, 25 (1960)
Nuessle AC, Am. Dyest. Rept., 47, 465 (1958)
Arie R, Arie O, J. Appl. Polym. Sci., 23, 797 (1979)
Willard JJ, Wondra RE, Text. Res. J., 40, 203 (1970)
Miller B, Meisen CH, Text. Chem Colour, 2, 35 (1970)
Kinoshita M, Hozumi K, Jpn. Anal., 14, 352 (1965)
Rath H, Herbolsheimer E, Stapt S, Text. Res. J., 30, 201 (1960)
Bellamy LJ, "The Infra-red Spectra of Complex Molecules," 4th ed., 311, Methuen and Co. Ltd., London (1966)
Bellamy LJ, "The Infra-red Spectra of Complex Molecules," 4th ed., 331, Methuen and Co. Ltd., London (1966)
Bellamy LJ, "The Infra-red Spectra of Complex Molecules," 4th ed., 179, Methuen and Co. Ltd., London (1966)
Bellamy LJ, "The Infra-red Spectra of Complex Molecules," 4th ed., 27, Methuen and Co. Ltd., London (1966)
Lecomte T, C.R. Acad. Sci. Paris., 216, 339 (1943)
Torkington T, Proc. Roy. Soc. A, 184, 3 (1945)
Nishi I, "Surfactant Handbook," 18th ed., 307, Sankyo Tosho Co., Tokyo (1979)
Lyons JW, "The Chemistry and Uses of Fire Retardants," 1st ed., 169, John Wiley and Sons, Inc., New York (1970)
Mok YI, HWAHAK KONGHAK, 15(4), 211 (1977)
Liggett RW, Bull. South Res. Inst., 21, 5 (1968)

[Referenced By]

[1] Textile Flammability and Consumer Safety, Gdi Occasional Publication No. 45, Ruschlikzon-Zurich (1969)

[2] Martin EP, Ciba Rev. (1969)

[3] Sayers LW, Text. Inst. Ind., 3, 168 (1965)

[4] Tessoro GC, Textilveredlung, 1, 208 (1966)

[5] Tolgyesi WS, Krasny JF, Text. Res. J., 37, 298 (1967)

[6] Miles TD, Delasanta AC, Text. Res. J., 38, 273 (1968)

[7] Barker RH, Cell. Chem. Appl., 423 (1985)

[8] Ko SW, Ha WS, J. Korean Fiber Soc., 14, 18 (1977)

[9] Granzow A, Ferrillo RG, Wilson A, J. Appl. Polym. Sci., 21, 1687 (1977)

[10] Avondo G, Vovelle C, Delbourgo R, Combust. Flame, 31, 7 (1978)

[11] Holme L, Patel SR, J.S.D.C., 96, 224 (1980)

[12] Lee ES, Song KG, Ko SW, J. Korean Fiber Soc., 28, 60 (1991)

[13] Lee ES, Song KG, Ko SW, J. Korean Fiber Soc., 28, 66 (1991)

[14] Coover HW, Dickey JB, U.S. Patent, 2,763,631 (1956)

[15] Palethorpe G, U.S. Patent, 3,318,978 (1967)

[16] Park HS, Kim YG, Bea JS, J. Korean Oil Chem. Soc., 7, 31 (1990)

[17] Enders H, Pusch G, Am. Dyest. Rept., 49, 25 (1960)

[18] Nuessle AC, Am. Dyest. Rept., 47, 465 (1958)

[19] Arie R, Arie O, J. Appl. Polym. Sci., 23, 797 (1979)

[20] Willard JJ, Wondra RE, Text. Res. J., 40, 203 (1970)

[21] Miller B, Meisen CH, Text. Chem Colour, 2, 35 (1970)

[22] Kinoshita M, Hozumi K, Jpn. Anal., 14, 352 (1965)

[23] Rath H, Herbolsheimer E, Stapt S, Text. Res. J., 30, 201 (1960)

[24] Bellamy LJ, "The Infra-red Spectra of Complex Molecules," 4th ed., 311, Methuen and Co. Ltd., London (1966)

[25] Bellamy LJ, "The Infra-red Spectra of Complex Molecules," 4th ed., 331, Methuen and Co. Ltd., London (1966)

[26] Bellamy LJ, "The Infra-red Spectra of Complex Molecules," 4th ed., 179, Methuen and Co. Ltd., London (1966)

[27] Bellamy LJ, "The Infra-red Spectra of Complex Molecules," 4th ed., 27, Methuen and Co. Ltd., London (1966)

[28] Lecomte T, C.R. Acad. Sci. Paris., 216, 339 (1943)

[29] Torkington T, Proc. Roy. Soc. A, 184, 3 (1945)

[30] Nishi I, "Surfactant Handbook," 18th ed., 307, Sankyo Tosho Co., Tokyo (1979)

[31] Lyons JW, "The Chemistry and Uses of Fire Retardants," 1st ed., 169, John Wiley and Sons, Inc., New York (1970)

[32] Mok YI, HWAHAK KONGHAK, 15(4), 211 (1977)

[33] Liggett RW, Bull. South Res. Inst., 21, 5 (1968)