Journal of the American Ceramic Society, Vol.96, No.3, 697-700, 2013
In Situ Thermometry Measuring Temperature Flashes Exceeding 1,700 degrees C in 8 mol% Y2O3-Stablized Zirconia Under Constant-Voltage Heating
Using AC impedance spectroscopy as a means of in situ thermometry, temperature runaway over 1,500 degrees C within a few seconds was observed for the first time in dense 92mol% ZrO28mol% Y2O3 (8YSZ) ceramics heated under a constant voltage. Such runaway is especially pronounced when starting from a low background temperature in samples of a small surface-to-volume ratio, and is expected to be commonplace during flash sintering of porous ceramic cubes or cylinders. The method of AC impedance-based thermometry is applicable to other ceramics with a well-defined conduction mechanism at high temperature.