Salicylaldoxime에 의한 금속 추출에 관한 연구

신정호; 박상욱; 박대원; 이경수; 정갑섭

Journal of the Korean Industrial and Engineering Chemistry, Vol.4, No.1, 46-53, March, 1993

Export Citation

Salicylaldoxime에 의한 금속 추출에 관한 연구

A Study on Solvent Extraction of Metal by Salicylaldoxime

신정호, 박상욱, 박대원, 이경수, 정갑섭

초록

salicylaldoxime에 의한 Cu의 용매추출에 있어서 추출평형 및 추출속도 등을 고찰하였다. 흡광도 측정으로부터 oxime의 분배정수와 해리정수를 구하고, oxime-Cu착화합물의 안정도 상수와 분배정수, 분자흡광계수 및 추출평형정수를 결정하였다. chloroform 및 benzene 용매하에 salicylaldoxime에 의한 Cu의 추출 화학종은 1:2의 형태인 CuR₂였으며, 초기 추출속도실험으로부터 salicylaldoxime-chloroform에 의한 Cu의 총괄추출속도는 R=k[Cu²⁺][HR]^0.5/[H⁺]^0.4로 표시 되었다.

The kinetic and equilibrium characteristics of copper extraction by salicylaldoxime in chloroform and benzene were investigated. Equilibrium constants such as dissociation constant, distribution coefficient of salicylaldoxime and stability constant, distribution coefficient and molar extinction coefficient of oxime-Cu chelate were determined from absorbance. Extracted species of Cu-chelate were found to be CuR₂. Overall initial extraction rate of copper by salicylaldoxime in chloroform was expressed by the following equation : R=k[Cu²⁺][HR]^0.5/[H⁺]^0.4.

[References]

Dansei PR, Chiarizia R, Vandegrift GF, J. Phys. Chem., 84, 3455 (1980)
Preston J, Luklinska ZB, J. Inorg. Nucl. Chem., 42, 431 (1980)
Szymanowski J, Jeszka P, Ind. Eng. Chem. Process Des. Dev., 24, 244 (1985)
Komasawa I, Otake T, Yamada A, J. Chem. Eng. Jpn., 13, 130 (1980)
Komasawa I, Otake T, Muraoka T, J. Chem. Eng. Jpn., 13, 204 (1980)
Komasawa I, Otake T, Yamada A, J. Chem. Eng. Jpn., 13, 209 (1980)
Preston J, J. Inorg. Nucl. Chem., 42, 441 (1980)
Komasawa I, Otake T, Ind. Eng. Chem. Fundam., 22, 122 (1983)
Goto M, Kondo K, Nakashio F, J. Chem. Eng. Jpn., 22, 79 (1989)
Miyake Y, J. Chem. Eng. Jpn., 19, 117 (1986)
Chaiko DJ, Osseo-asare K, Sep. Sci. Technol., 23, 1423 (1988)
Pandey B, Kumar V, Bagchi D, Akerkar DD, Ind. Eng. Chem. Res., 28, 1664 (1989)
Adachi M, J. Chem. Eng. Jpn., 16, 109 (1983)
Agarwal JC, Beecher N, Hubred GL, AIChE Symp., 76, 35 (1979)
Miyake Y, Takenoshita Y, Teramoto M, J. Chem. Eng. Jpn., 16, 203 (1983)
Kawabata N, Sumiyoshi K, Tanka M, Ind. Eng. Chem. Res., 29, 1989 (1990)
Kondo K, Oishi J, Nakashio F, J. Chem. Eng. Jpn., 23, 365 (1990)

[1] Dansei PR, Chiarizia R, Vandegrift GF, J. Phys. Chem., 84, 3455 (1980)

[2] Preston J, Luklinska ZB, J. Inorg. Nucl. Chem., 42, 431 (1980)

[3] Szymanowski J, Jeszka P, Ind. Eng. Chem. Process Des. Dev., 24, 244 (1985)

[4] Komasawa I, Otake T, Yamada A, J. Chem. Eng. Jpn., 13, 130 (1980)

[5] Komasawa I, Otake T, Muraoka T, J. Chem. Eng. Jpn., 13, 204 (1980)

[6] Komasawa I, Otake T, Yamada A, J. Chem. Eng. Jpn., 13, 209 (1980)

[7] Preston J, J. Inorg. Nucl. Chem., 42, 441 (1980)

[8] Komasawa I, Otake T, Ind. Eng. Chem. Fundam., 22, 122 (1983)

[9] Goto M, Kondo K, Nakashio F, J. Chem. Eng. Jpn., 22, 79 (1989)

[10] Miyake Y, J. Chem. Eng. Jpn., 19, 117 (1986)

[11] Chaiko DJ, Osseo-asare K, Sep. Sci. Technol., 23, 1423 (1988)

[12] Pandey B, Kumar V, Bagchi D, Akerkar DD, Ind. Eng. Chem. Res., 28, 1664 (1989)

[13] Adachi M, J. Chem. Eng. Jpn., 16, 109 (1983)

[14] Agarwal JC, Beecher N, Hubred GL, AIChE Symp., 76, 35 (1979)

[15] Miyake Y, Takenoshita Y, Teramoto M, J. Chem. Eng. Jpn., 16, 203 (1983)

[16] Kawabata N, Sumiyoshi K, Tanka M, Ind. Eng. Chem. Res., 29, 1989 (1990)

[17] Kondo K, Oishi J, Nakashio F, J. Chem. Eng. Jpn., 23, 365 (1990)