Materials Chemistry and Physics, Vol.139, No.2-3, 375-382, 2013
Detached phenomenon: Its effect on the crystal quality of Ga(1-x)InxSb bulk crystal grown by the VDS technique
Vertical directional solidification (VDS) technique is used on the combined growth principals of the conventional methods since 1994, which leads to the detached growth. For evaluation of the detached growth, five bulk ingots of indium doped gallium antimonide GaSb:In (In = 0.5, 0.25, 0.15) have been grown without the seed, without contact to the ampoule wall, without coating and without external pressure. The gap is attributed to compensate the differential thermal dilatation that is grown with the reduced diameter than the diameter of the ampoule. VDS experiments have been proved that the sum of the contact angle and growth angle is large enough to allow detachment without any additional pressure difference under the melt to offset hydrostatic pressure. A meniscus forms at the bottom of the melt, the capillarity effect establishes due to which spontaneous gap could be created by the melt free surface, thus no thermal shear stress and thermo-mechanical stresses at the interface. Detached grown bulk GaSb:In crystals showed superior crystal quality with the highest physical properties and mobility than the crystals grown ever. The axial and radial composition profile of the grown GaSb:In ingots showed variation <= 10%. From the conical region, dislocation density decreases in the growth direction and reaches less than 10(3) cm(-2). (C) 2012 Elsevier B.V. All rights reserved.
Keywords:Semiconductor;Crystal growth;Solidification;Fourier transform infrared spectroscopy (FTIR);Raman spectroscopy and scattering;Crystal structure;Hall Effect