용제형 저기포성 정련제의 제조에 관한 연구

박은경; 박홍수; 김영근

Journal of the Korean Industrial and Engineering Chemistry, Vol.4, No.2, 358-364, June, 1993

Export Citation

용제형 저기포성 정련제의 제조에 관한 연구

A Study on the Preparation of Solvent Type Low Foaming Scouring Agents

박은경, 박홍수, 김영근

초록

2-Ethylhexylaminoethyl sulfate, Na-dioctyl sulfosuccinate, Newpol PP-2000, MJU-100, 에틸렌글리콜 및 유기용제 등을 블렌딩하여 저기포성 정련제(SLFS)를 제조하였다. SLFS로서 여러가지 물성시험을 해 본 결과, SLFS-2는 정련효과, 침투력, 유화력, 내알칼리성 등이 양호하였으며, 수질오염에 대한 영향이 크지 않았다. 또한 SLFS-2는 Ross & Miles법에 의한 거품생성 직후의 기포력이 포고 8㎜로 나타났고, Ross & Clark법에 의한 기포력이 30℃에서는 포고 300㎜ 이하로, 80℃에서는 15㎜를 각각 나타내어 양호한 저기포성 정련제임이 입증되었다.

Low foaming scouring agents(SLFS) were prepared by blending of 2-ethylhexylaminoethyl sulfate, Na-dioctyl sulfosuccinate, Newpol PP-2000, MJU-100, ethylene glycol and organic solvent. As the results of several tests, SLFS-2 showed good scouring effect, penetrating ability, emulsifiability and anti-alkaline property, and showed not much water pollution. The foaming power of SLFS-2 measured by Ross & Mites method was 8㎜ foam height immediately after foaming. And the foaming power of SLFS-2 measured by Ross & Clark method were less than 300mm foam height at 30℃, and 15㎜ at 80℃. As a result, SLFS-2 was proved as a good low foaming scouring agent.

[References]

Vora B, Pujado P, Imai T, Fritsch T, Chem. Ind., 19, 187 (1990)
Kimura M, Komaki M, Nakajima T, Nakahara H, Fukuda K, J. Am. Oil Chem. Soc., 67, 698 (1990)
Drozd JC, Desai DD, J. Am. Oil Chem. Soc., 68, 59 (1991)
Hellsten KE, Klingberg AW, Karlsson BT, J. Am. Oil Chem. Soc., 66, 1381 (1989)
Trounson ME, Mclaughlin JR, Robinson PW, Text. Res. J., 58, 455 (1988)
Sheridan GP, Dyer, 164, 28 (1980)
Sabia AJ, Am. Dyest. Reptr., 71, 45 (1982)
Gawish SM, Am. Dyest. Reptr., 73, 38 (1984)
Sabia AJ, Text. Chem. Colorist, 12, 178 (1980)
Ayala GA, Kamat S, Beckman EJ, Russell AJ, Biotechnol. Bioeng., 39, 806 (1992)
Murata M, Hoshino E, Yokosuka M, Suzuki A, J. Am. Oil Chem. Soc., 68, 553 (1991)
Kaminsky GJ, Drying Technol., 9, 709 (1991)
Malmos H, Chem. Ind., 19, 183 (1990)
Wrigley AN, Smith FD, Stirton AJ, J. Am. Oil Chem. Soc., 34, 39 (1957)
Osipow L, Snell FD, Finehler A, Ind. Eng. Chem., 48, 1454 (1956)
Weil JK, Koos RE, Linfield WM, Parris N, J. Am. Oil Chem. Soc., 56, 874 (1979)
Schoberl VP, Bock KJ, Tenside, 17, 262 (1980)
Park HS, J. Korean Fiber Soc., 15, 32 (1978)
McBain JW, McHan H, J. Am. Chem. Soc., 70, 3838 (1948)
Churchfield JW, U.S. Patent, 3,746,653 (1973)
Vanness GF, Tiernan TO, Hanes MS, Reynolds CJ, Garrett JH, Wagel DJ, Solch JG, Chemosphere, 20, 1611 (1990)
Muller W, Diamond DM, J. Phys. Chem., 70, 3469 (1966)
Schulman JH, Teorell T, Trans. Faraday Soc., 54, 1337 (1938)
Ross S, "The Inhibitors of Foaming, Engineering and Science Series 63," Rensselaer, New York (1950)
Gunderson LO, Ind. Eng. Chem., 40, 1343 (1948)
Fineman MN, Brown GL, Myers RJ, J. Phys. Chem., 56, 963 (1952)
Cooper RS, Urfer AD, J. Am. Oil Chem. Soc., 41, 337 (1964)
Crook EH, Fordyce DB, J. Am. Oil Chem. Soc., 41, 231 (1964)

[Referenced By]

[1] Vora B, Pujado P, Imai T, Fritsch T, Chem. Ind., 19, 187 (1990)

[2] Kimura M, Komaki M, Nakajima T, Nakahara H, Fukuda K, J. Am. Oil Chem. Soc., 67, 698 (1990)

[3] Drozd JC, Desai DD, J. Am. Oil Chem. Soc., 68, 59 (1991)

[4] Hellsten KE, Klingberg AW, Karlsson BT, J. Am. Oil Chem. Soc., 66, 1381 (1989)

[5] Trounson ME, Mclaughlin JR, Robinson PW, Text. Res. J., 58, 455 (1988)

[6] Sheridan GP, Dyer, 164, 28 (1980)

[7] Sabia AJ, Am. Dyest. Reptr., 71, 45 (1982)

[8] Gawish SM, Am. Dyest. Reptr., 73, 38 (1984)

[9] Sabia AJ, Text. Chem. Colorist, 12, 178 (1980)

[10] Ayala GA, Kamat S, Beckman EJ, Russell AJ, Biotechnol. Bioeng., 39, 806 (1992)

[11] Murata M, Hoshino E, Yokosuka M, Suzuki A, J. Am. Oil Chem. Soc., 68, 553 (1991)

[12] Kaminsky GJ, Drying Technol., 9, 709 (1991)

[13] Malmos H, Chem. Ind., 19, 183 (1990)

[14] Wrigley AN, Smith FD, Stirton AJ, J. Am. Oil Chem. Soc., 34, 39 (1957)

[15] Osipow L, Snell FD, Finehler A, Ind. Eng. Chem., 48, 1454 (1956)

[16] Weil JK, Koos RE, Linfield WM, Parris N, J. Am. Oil Chem. Soc., 56, 874 (1979)

[17] Schoberl VP, Bock KJ, Tenside, 17, 262 (1980)

[18] Park HS, J. Korean Fiber Soc., 15, 32 (1978)

[19] McBain JW, McHan H, J. Am. Chem. Soc., 70, 3838 (1948)

[20] Churchfield JW, U.S. Patent, 3,746,653 (1973)

[21] Vanness GF, Tiernan TO, Hanes MS, Reynolds CJ, Garrett JH, Wagel DJ, Solch JG, Chemosphere, 20, 1611 (1990)

[22] Muller W, Diamond DM, J. Phys. Chem., 70, 3469 (1966)

[23] Schulman JH, Teorell T, Trans. Faraday Soc., 54, 1337 (1938)

[24] Ross S, "The Inhibitors of Foaming, Engineering and Science Series 63," Rensselaer, New York (1950)

[25] Gunderson LO, Ind. Eng. Chem., 40, 1343 (1948)

[26] Fineman MN, Brown GL, Myers RJ, J. Phys. Chem., 56, 963 (1952)

[27] Cooper RS, Urfer AD, J. Am. Oil Chem. Soc., 41, 337 (1964)

[28] Crook EH, Fordyce DB, J. Am. Oil Chem. Soc., 41, 231 (1964)