화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.39, No.2, 238-240, 1994
Molar Excess Volumes of Binary and Ternary Mixtures Containing Chloroaniline
Molar excess volumes, V(E), for m-chloroaniline + benzene, + toluene, + o-xylene, + m-xylene, and + p-xylene, m-chloroaniline + benzene + toluene, and m-chloroaniline + benzene + o-xylene have been measured as a function of composition at 308.15 K. V(E) values for the binary mixtures are negative for all the systems over the entire range of composition and for an equimolar composition vary in the order o-xylene > toluene > m-xylene > benzene > p-xylene. On the other hand while V(E) values for m-chloroaniline + benzene + toluene are negative over the whole composition range, those for m-chloroaniline + benzene + o-xylene vary from positive to negative depending on the mole fraction of each of the components.