Distribution coefficients of 2,4-dichlorophenol between supercritical carbon dioxide and water are measured at 298.15 and 319.15 K over the pressure range 11-23 MPa using a single-stage equilibrium cell. The data are modeled by the Peng-Robinson equation of state with modified mixing rules. The data are also compared to literature data on distribution coefficients of phenol and p-chlorophenol.