수산화라디칼과 오존에 의한 수중 천연 지방산 분해 제거 연구

원정하; 김용주; 고장면; 송근한; 이창훈; Latifatu Mohammed; Jung Ha Won; Yong Joo Kim; Jang Myoun Ko; Keun Han Song; Chang Hoon Lee

Korean Chemical Engineering Research, Vol.51, No.4, 523-526, August, 2013

Export Citation

수산화라디칼과 오존에 의한 수중 천연 지방산 분해 제거 연구

Purification of the Waste Water Containing Natural Fatty Oil by Hydroxy Radical and Ozone

, 원정하, 김용주, 고장면^†, 송근한¹, 이창훈¹

한밭대학교 화학생명공학과, 305-719 대전광역시 유성구 덕명동 산 16-1
¹(주) 브이케이테크, 305-719 대전광역시 유성구 테크노1로 11-3 배재대학교 산학협력관 S103호

Latifatu Mohammed, Jung Ha Won, Yong Joo Kim, Jang Myoun Ko^†, Keun Han Song¹, and Chang Hoon Lee¹

Department of Chemical Engineering, Hanbat University, San 16-1 Deongmyeong-dong, Yuseong-gu, Daejeon 305-719, Korea
¹VK-Technology Corporation, S103 Pai Chai SanHak, 11-3 Techno 1-ro, Yuseong-gu, Daejeon 305-719, Korea

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초록

본 연구에서는 수질정화 기술개발을 위하여 수산화라디칼 및 오존 발생기를 이용하여 수중에 존재하는 천연 지방산 분해 제거 연구를 수행하였다. 천연 지방산은 수산화라디칼 및 오존에 의하여 1차 분해반응 형태로 제거되었으며, 천연 지방산의 분해반응에서 수산화라디칼 단독으로 사용하는 것 보다 오존과 함께 사용한 경우 분해 효율을 크게 향상시킬 수 있음을 알 수 있었다. 또한, 천연 지방산이 수산화라디칼과 오존에 의해 분해되는 화학반응 기구를 제안하였다.

In order to purify the waste water containing natural fatty oil, hydroxy radical and/or ozone are used to remove the fatty oil dispersed in the waste water. The fatty oil is decomposed by oxidation reaction through hydroxy radical and ozone, and eliminated as a function of first order reaction. It is clearly confirmed that the fatty oil in waste water can be effectively removed much more in the use of both hydroxy radical and ozone than only hydroxy radical as an oxydant. In addition, the decomposition chemical reaction mechanism of the fatty oil by hydroxy radical and ozone is proposed.

Keywords:Hydroxy Radical;Ozone;Fatty Oil;Waste Water;Water Purification

[References]

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Guzzella L, Feretti D, Monarca S, Water Res., 36(17), 4307 (2002)
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[1] Kwon TO, Park BB, Moon IS, Korean Chem. Eng. Res., 45(6), 648 (2007)

[2] Ryu WR, Cho MH, Choi JS, Yang YW, J. KSEE., 20(7), 927 (1998)

[3] Kang DZ, Hong YP, Lee JH, Kor. J. Microbiol. Biotechnol., 31(2), 177 (2003)

[4] Kim JH, Rhee CH, Woo CJ, Joo GJ, Seo SK, Park HD, Kor. J. Appl. Microbiol. Biotechnol., 27(2), 118 (1999)

[5] Wang J, Chen L, Shi H, Qian Y, Chemosphere., 41(8), 1245 (2000)

[6] Lee SM, Jo HJ, Kim JG, Jung JH, J. KSWQ., 20(5), 452 (2004)

[7] Lee JW, Chung SJ, Balaji S, Kokovkin VV, Moon IS, Chemosphere., 68(6), 1067 (2007)

[8] Choi JW, Song HK, Lee W, Koo KK, Han C, Na BK, Korean J. Chem. Eng., 21(2), 398 (2004)

[9] Ramesh T, Kwon TO, Jun JC, Balaji S, Matheswaran M, Moon IS, J.Hazard. Mater., 142(1-2), 308 (2006)

[10] Andreozzi R, Marotta R, Water Res., 38(5), 1225 (2004)

[11] Ramesh T, Kwon TO, Moon IS, J. Environ. Sci. Health Part A., 41(8), 1685 (2006)

[12] Ramesh T, Kwon TO, Moon IS, J. Environ. Sci. Health Part A., 41(8), 1685 (2006)

[13] Guzzella L, Feretti D, Monarca S, Water Res., 36(17), 4307 (2002)

[14] Behnajady MA, Modirshahla N, Fathi H, J. Hazard. Mater., 136(3), 816 (2006)

[15] Hwang SC, Bouwer EJ, Larson SL, Davis JL, J. Hazard. Mater., 108(1-2), 61 (2004)

[16] Jung JH, Suh H, Mohseni M, Water Res., 38(10), 2596 (2004)

[17] Criegee R, R. Angew. Chem., 87, 745 (1975)

[18] Yoa SJ, Cho YS, Kim JH, Korean J. Chem. Eng., 22(3), 364 (2005)