화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.4, 1257-1266, July, 2013
DOI10.1016/j.jiec.2012.12.026  Export Citation
Synthesis of highly carboxylated latex particles using a power feed process
R. Santillan, E. Nieves, C.P. Alejandre, C. Go´mez-Yan˜ez, J.M. del Rıo1, H. Dorantes-Rosales, M.E. Navarro-Clemente, and M. Corea†
  • Instituto Polite´cnico Nacional, ESIQIE, UPALM, Edificio Z-6, Primer piso, San Pedro Zacatenco, Del. Gustavo A. Madero, Me´xico D.F., Mexico
  • 1Instituto Mexicano del Petro´leo, Programa de Aseguramiento de la Produccion, Eje Central La´zaro Ca´rdenas No. 52, San Bartolo Atepehuacan, Del. Gustavo A. Madero, Me´xico D.F., Mexico
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Two series of highly carboxylated latex particles were synthesized via a power feed process. The concentration carboxylic groups were varied inside the particles and a gradient in the concentration from the interior to the surface was created. The power feed process, proposed by Bassett et al., was used for the synthesis of the functionalized materials and a mathematical model was proposed for this process and theoretical predictions for the concentration of carboxylic groups inside the particles were corroborated with experimental results. A methodology based on thermodynamic formalism is proposed to study the response of these materials to ion exchange.
Keywords:Power feed process;Highly carboxylated particles;Functionalized latex;Architecture molecular;Hydrogels and smart materials
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