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Journal of Industrial and Engineering Chemistry, Vol.19, No.4, 1413-1419, July, 2013
Study on the solid acid catalysts in biodiesel production from high acid value oil
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In an effort to make use of high acid value oils for biodiesel production, various solid acid catalysts such as cesium-doped heteropoly tungstate (CsHPW), 20%TPW/ZrO2, 20%WO3/ZrO2, 20%TPW/g-Al2O3, and 20%TPW/SiO2 were prepared and evaluated. Leaching of the active species from the catalyst during actual reaction conditions was also investigated to estimate the contribution of homogeneous catalysis. CsHPW was found to be highly active and most stable among other acid catalysts and a maximum conversion of 90% was obtained at the optimum reaction conditions. Further, the recycled use of the selected catalyst was also examined.
- Kulkarni MG, Dalai AK, Ind. Eng. Chem. Res., 45(9), 2901 (2006)
- Brito A, Borges ME, Garin M, Hernandez A, Energy Fuels, 23, 2952 (2009)
- Jacobson K, Gopinath R, Meher LC, Dalai AK, Appl. Catal. B: Environ., 85(1-2), 86 (2008)
- Refaat AA, International Journal of Environmental Science and Technology., 7, 183 (2010)
- Kim HJ, Kang BS, Kim MJ, Park YM, Kim DK, Lee JS, Lee KY, Catal. Today, 93-95, 315 (2004)
- Lotero E, Liu YJ, Lopez DE, Suwannakarn K, Bruce DA, Goodwin JG, Ind. Eng. Chem. Res., 44(14), 5353 (2005)
- Tanawannapong Y, Kaewchada A, Jaree A, J. Ind. Eng. Chem., 19(1), 37 (2013)
- Canakci M, Van Gerpen J, Transactions of the American society of Agricultural Engineers., 44, 1429 (2001)
- Di Serio M, Tesser R, Pengmei L, Santacesaria E, Energy Fuels, 22(1), 207 (2008)
- Kozhevnikov IV, Chem. Rev., 98(1), 171 (1998)
- Okuhara T, Chem. Rev., 102(10), 3641 (2002)
- Wu Y, Ye XK, Yang XG, Wang XP, Chu WL, Hu YC, Ind. Eng. Chem. Res., 35(8), 2546 (1996)
- Okuhara T, Nishimura T, Watanabe H, Misono M, Journal of Molecular Catalysis., 74, 247 (1992)
- Izumi Y, Hisano K, Hida T, Appl. Catal. A: Gen., 181(2), 277 (1999)
- Kulkarni MG, Gopinath R, Meher LC, Dalai AK, Green Chemistry., 8, 1056 (2006)
- Corma A, Martinez A, Martinez C, J. Catal., 164(2), 422 (1996)
- Izumi Y, Hasebe R, Urabe K, Journal of Catalysis., 84, 402 (1983)
- Alsalme A, Kozhevnikova EF, Kozhevnikov IV, Appl. Catal. A: Gen., 349(1-2), 170 (2008)
- Dias JA, Caliman E, Claidia S, Dias L, Microporous and Mesoporous Materials., 76, 221 (2004)
- Okuhara T, Nakato T, Catalysis Survey from Japan., 2, 31 (1998)
- Kimura M, Nakato T, Okuhara T, Appl. Catal. A: Gen., 165(1-2), 227 (1997)
- McMonagle JB, Moffat JB, Journal of Colloid and Interface Science., 101, 479 (1984)
- Narasimharao K, Brown DR, Lee AF, Newman AD, Siril PF, Tavener SJ, Wilson K, J. Catal., 248(2), 226 (2007)
- Okuhara T, Watanabe H, Nishimura T, Inumaru K, Misono M, Chemistry of Materials., 12, 2230 (2000)
- Okuhara T, Mizuno N, Misono M, Advances in Catalysis., 41, 113 (1996)
- Furuta S, Matsuhashi H, Arata K, Catalysis Communications., 5, 721 (2004)
- Freedman B, Butterfield RO, Pryde EH, Journal of the American Oil Chemists Society., 63, 1375 (1986)
- Freedman B, Pryde EH, Mounts TL, Journal of the American Oil Chemists Society., 61, 1638 (1984)
- Park YM, Lee DW, Kirn DK, Lee JS, Lee KY, Catal. Today, 131(1-4), 238 (2008)
- Keyes DB, Industrial and Engineering Chemistry., 24, 1096 (1932)
- Van Gerpen J, Fuel Process. Technol., 86(10), 1097 (2005)
- Saraf S, Thomas B, Process Saf. Environ. Protect., 85(B5), 360 (2007)
- Wang Y, Ou SY, Liu PZ, Zhang ZS, Energy Conv. Manag., 48(1), 184 (2007)
- Ozbay N, Oktar N, Tapan NA, Fuel, 87(10-11), 1789 (2008)
- Jain S, Sharma MP, Rajvanshi S, Fuel Process. Technol., 92(1), 32 (2011)
- West AH, Posarac D, Ellis N, Bioresour. Technol., 99(14), 6587 (2008)