Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts

Chang Hun Lee; Yin Hua Jin; Joongyeon Kim; Sun Hee Park; Byung-Hee Chun; Sung Hyun Kim

Journal of Industrial and Engineering Chemistry, Vol.19, No.5, 1443-1447, September, 2013

DOI10.1016/j.jiec.2013.01.007 Export Citation

Catalytic dechlorination of C5 compounds over metal-oxide/ZSM-5 catalysts

Chang Hun Lee, Yin Hua Jin, Joongyeon Kim, Sun Hee Park, Byung-Hee Chun, and Sung Hyun Kim^†

Department of Chemical and Biological Engineering, Korea University, Anam-dong, Seongbuk-Gu, Seoul 136-701, Republic of Korea

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In this research, the dechlorination of 2-chloro-2-butene in C5 oil from the fluid catalytic cracking (FCC) process was performed through a catalytic reaction. Metal oxides were used as active materials and ZSM-5 was used as the supporting material for the catalysts; the metal was cobalt, iron, or manganese. After the preparation of three types of metal-oxide/ZSM-5 catalysts through the ion-exchange method, the activities and characteristics of each catalyst were evaluated. Through screening tests, the Co3O4/ZSM-5 catalyst was selected as the dechlorination catalyst, and the performance of catalysts containing different amounts of Co3O4 relative to ZSM-5 were tested.

Keywords:C5 compounds;Dechlorination;Metal oxide/ZSM-5;Ion exchange;Cobalt oxide

[References]

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Joseph W. Wilson, Fluid Catalytic Cracking Technology and Operation, 1st ed., Pennwell Books, Oklahoma (1997)
Venuto PB, Habib TE, Fluid Catalytic Cracking with Zeolite Catalysts, 1st ed., Marcel Dekker, New York (1979)
Arandes JM, Erena J, Bilbao J, Lopez-Valerio D, De la Puente G, Ind. Eng. Chem. Res., 42(17), 3952 (2003)
Aguado J, Serrano DP, Escola JM, Ind. Eng. Chem. Res., 47(21), 7982 (2008)
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He N, Li PJ, Zhou YC, Ren WX, Fan SX, Verkhozina VA, J. Hazard. Mater., 164(1), 126 (2009)
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Zhou Q, Tang C, Wang YZ, Zheng L, Fuel, 83(13), 1727 (2004)
Lv B, Zhao G, Li D, Liang C, Polymer Degradation and Stability., 94(7), 1047 (2009)
Lopez A, de Marco I, Caballero BM, Laresgoiti MF, Adrados A, Aranzabal A, Appl. Catal. B: Environ., 104(3-4), 211 (2011)
Pearce R, William R. Patterson, Catalysis and Chemical Processes, 1st ed., Wiley, New York (1981)
Fierro JLG, Juan F. Garcoa De La Banda, Catalysis Review., 28(2-3), 265 (1986)
Okada T, Analytical Chemistry., 64(6), 589 (1992)

[Referenced By]

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[1] Liu GL, Xu XR, Gao JS, Energy Fuels, 17(3), 625 (2003)

[2] Joseph W. Wilson, Fluid Catalytic Cracking Technology and Operation, 1st ed., Pennwell Books, Oklahoma (1997)

[3] Venuto PB, Habib TE, Fluid Catalytic Cracking with Zeolite Catalysts, 1st ed., Marcel Dekker, New York (1979)

[4] Arandes JM, Erena J, Bilbao J, Lopez-Valerio D, De la Puente G, Ind. Eng. Chem. Res., 42(17), 3952 (2003)

[5] Aguado J, Serrano DP, Escola JM, Ind. Eng. Chem. Res., 47(21), 7982 (2008)

[6] Kortunov P, Vasenkov S, Ka¨ rger J, Fe´ Elı´a M, Perez M, Sto¨ cker M, Papadopoulos GK, Theodorou D, Drescher B, McElhiney G, Bernauer B, Krystl V, Kocirˇı´k M, Zika´nova´ A, Jirglova´ H, Berger C, Gla¨ ser R, Weitkamp J, Hansen EW, Chemistry of Materials., 17(9), 2466 (2005)

[7] Speight JG, The Chemistry and Technology of Petroleum, 3rd ed., CRC Press, New York (2006)

[8] Lu Y, He MY, Shu XT, Zong BN, Energy Fuels, 17(4), 1040 (2003)

[9] Grause G, Matsumoto S, Kameda T, Yoshioka T, Ind. Eng. Chem. Res., 50(9), 5459 (2011)

[10] He N, Li PJ, Zhou YC, Ren WX, Fan SX, Verkhozina VA, J. Hazard. Mater., 164(1), 126 (2009)

[11] Jalil AA, Triwahyono S, Razali NAM, Hairom NHH, Idris A, Muhid MNM, Ismail A, Yahaya NAM, Ahmad NAL, Dzinun H, J. Hazard. Mater., 174(1-3), 581 (2010)

[12] Demirbas A, Gullu D, Energy Educational Science and Technology., 1(2), 111 (1998)

[13] Demirbas A, Energy Educational Science and Technology., 6(1), 19 (2000)

[14] Lingaiah N, Uddin MA, Muto A, Imai T, Sakata Y, Fuel., 80(13), 1901 (2001)

[15] Zhou Q, Tang C, Wang YZ, Zheng L, Fuel, 83(13), 1727 (2004)

[16] Lv B, Zhao G, Li D, Liang C, Polymer Degradation and Stability., 94(7), 1047 (2009)

[17] Lopez A, de Marco I, Caballero BM, Laresgoiti MF, Adrados A, Aranzabal A, Appl. Catal. B: Environ., 104(3-4), 211 (2011)

[18] Pearce R, William R. Patterson, Catalysis and Chemical Processes, 1st ed., Wiley, New York (1981)

[19] Fierro JLG, Juan F. Garcoa De La Banda, Catalysis Review., 28(2-3), 265 (1986)

[20] Okada T, Analytical Chemistry., 64(6), 589 (1992)