화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.5, 1517-1524, September, 2013
DOI10.1016/j.jiec.2013.01.018  Export Citation
Vapor phase synthesis of cyclopentanone over nanostructured ceria-zirconia solid solution catalysts
Putla Sudarsanam, Lakshmi Katta1, Gode Thrimurthulu2, and Benjaram M. Reddy†
  • Inorganic and Physical Chemistry Division, CSIR – Indian Institute of Chemical Technology, Uppal Road, Hyderabad 500 607, India
  • 1Dipartimento di Chimica, Fisica e Ambiente, Universita` di Udine, via Cotonificio 108, 33100 Udine, Italy
  • 2Laboratoire de Reactivite de Surface, Universite Pierre et Marie Curie, UMR 7197 CNRS, 4 place Jussieu, F75252 Paris Cedex 05, France
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The present study was undertaken to develop a novel and easy practical approach for synthesis of cyclopentanone, a versatile industrial ingredient. Accordingly, ceria.zirconia based nano-oxide catalysts, namely, CexZr1-xO2 and CexZr1-xO2/M (M = SiO2 and Al2O3) were prepared and evaluated for the title reaction. The physicochemical characterization has been achieved using different techniques, namely, XRD, BET surface area, XPS, Raman, OSC, and HREM. The catalytic results revealed that CexZr1-xO2 based nano-oxides are promising heterogeneous catalysts for synthesis of cyclopenta-none. Amongst, the CexZr1-xO2/Al2O3 catalyst exhibited 100% conversion with 75% desired cyclopentanone product selectivity owing to its favorable physicochemical characteristics.
Keywords:Ceria-zirconia;Support metal oxide;Lattice strain;Oxygen vacancies;Oxygen storage capacity;Cyclopentanone
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