A circulation-type apparatus was constructed to measure high-pressure vapor-liquid equilibria. The vapor-liquid equilibria for carbon dioxide + linalool at 313.2 K from 4.00 to 7.99 MPa, at 323.2 K from 4.00 to 9.78 MPa, and at 333.2 K from 5.00 to 10.96 MPa were measured. The results were correlated by the Peng-Robinson equation of state using conventional mixing rules with two interaction parameters.