화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.40, No.5, 1097-1100, 1995
Excess Molar Enthalpies of an Alkanol Plus a Cyclic Ether at 298.15 K
Excess molar enthalpies H-m(E) measured at 298.15 K using a flow calorimeter are reported for 12 mixtures of methanol, ethanol, propan-1-ol, or propan-2-ol + tetrahydrofuran (THF), + tetrahydropyran (THP), or + 1,4-dioxane. For all of the systems investigated, H-m(E) is strongly positive over the whole mole fraction range and increases in the order methanol < ethanol < propan-1-ol < propan-2-ol. H-m(E) (maximum) depends on both the size of the cycloether ring and the number of carbon atoms in the alkanol molecule. The results are explained in terms of the strong self-association exhibited by the alkanol and the cross-association of the O ... HO specific interaction.