Industrial & Engineering Chemistry Research, Vol.52, No.18, 6221-6233, 2013
CT Scan Study of Immiscible Foam Flow in Porous Media for Enhancing Oil Recovery
A systematic CT-scan-aided laboratory study of N-2 foam in Bentheimer sandstone cores is reported. The aim of the study was to investigate whether foam can improve oil recovery from clastic reservoirs subject to immiscible gas flooding. Foam was generated in situ in water-flooded sandstone cores by coinjecting gas and surfactant solution at fixed foam quality. It was stabilized using two surfactants, namely, C14-16 alpha-olefin sulfonate (AOS) and mixtures of AOS and a polymeric fluorocarbon (FC) ester. The effects of surfactant concentration, injection direction, surfactant preflush, and core length on foam behavior were examined in detail. Stable foams were obtained in the presence of waterflood residual oil. It was found that foam strength (mobility reduction factor) increases with surfactant concentration. Foam development and, correspondingly, oil recovery without surfactant preflush were delayed compared to the case with preflush. Gravity-stable foam injection caused a rapid increase in foam strength and an incremental oil recovery almost twice that for unstable flow conditions. Core floods revealed that the incremental oil recovery by foam was as much as (23 +/- 2)% of the oil initially in place after injection of 4.0 pore volumes (PV) of foam (equal to the injection of 0.36 PV of surfactant solution). Incremental oil recovery was only (5.0 +/- 0.5)% for gas flooding under the same injection conditions. It appears that oil production by foam flooding occurs by the following main mechanisms: (1) residual oil saturation to foam flooding is lower than that to water flooding; (2) formation of an oil bank in the first few injected pore volumes, coinciding with a large increase of capillary number; and (3) a long tail production due to the transport of tiny oil droplets within the flowing foam at a fairly constant capillary number. The observations of this study support the concept that foam is potentially an efficient enhanced oil recovery (EOR) method.