Five acetate-based ionic liquids (AcAILs) [C(n)mim]{OAc} (n = 2, 3, 4, 5, 6) (1-alkyl-3-methylimidazolium acetate) were prepared by the neutralization method and characterized by H-1 NMR spectroscopy and differential scanning calorimetry (DSC). Their density, surface tension, and refractive index were measured at 298.15 to 338.15 K. Since the AcAILs can form strong hydrogen bonds with water, small amounts of water are difficult to remove by common methods. In order to eliminate the effect of the impurity water, the standard addition method (SAM) was applied to these measurements. On the basis of the experimental data, the molecular volume (sum of positive and negative ion volumes), V-m, of [C(n)mim][OAc](n = 2, 3, 4, 5, 6), the entropy of surface formation, S-a, the Gibbs energy of surface formation E-a, the parachor, P, and the molar refraction, R-m, the polarization coefficient, alpha(p), were calculated. The results show that E-a, P, and R-m are approximately temperature-independent and the contribution to these properties per methylene (-CH2-) on alkyl chain of [C(n)mim][OAc](n = 2, 3, 4, 5, 6) was discussed. According to both Kabo's and Rebelo's methods, the molar enthalpy of evaporation of the [C(n)mim][OAc](n = 2, 3, 4, 5,6) was estimated using surface tension and molar volume. In the same time, the surface tension of the AcAILs may be estimated using the parachor and the refractive index. The estimated values of the surface tension and the corresponding experimental one are extremely similar.