Three novel uranyl borophosphates, Ag-2(NH4)(3)[(UO2)(2){B3O(PO4)(4)(PO4H)(2)}]H2O (AgNBPU-1), Ag(2-x)(NH4)(3)[(UO2)(2){B2P5O(20-x)(OH)(x)}] (x = 1.26) (AgNBPU-2), and Ag(2-x)(NH4)(3)[(UO2)(2){B2P(5-y)-AsyO(20-x)(OH)(x)}] (x = 1.43, y = 2.24) (AgNBPU-3), have been prepared by the H3BO3-NH4H2PO4/NH4H2AsO4 flux method. The structure of AgNBPU-1 has an unprecedented fundamental building block (FBB), composed of three BO4 and six PO4 tetrahedra which can be written as 9 square:[Phi] square < 3 square >square vertical bar square < 3 square >square vertical bar square < 3 square >square vertical bar. Two Ag atoms are linearly coordinated; the coordination of a third one is T-shaped. AgNBPU-2 and AgNBPU-3 are isostructural and possess a FBB of two BO4 and five TO4 (T = P, As) tetrahedra (7 square:square < 4 square >)square vertical bar square). AgNBPU-3 is a solid solution with some PO4 tetrahedra of the AgNBPU-2 end-member being substituted by AsO4. Only two out of the three independent P positions are partially occupied by As, resulting in site dependent isomorphism. The three compounds represent the first actinide borophosphates.