마이크로에멀젼에서 리파아제 촉매에 의한 고급지방산 모노글리세리드의 생성에 있어 최적 효과

노윤찬; 남기대; 김진탁; 조경행

Journal of the Korean Industrial and Engineering Chemistry, Vol.5, No.2, 209-214, April, 1994

The Optimum Effect of Long Chain Fatty Monog1yceride from Microemulsion by Lipase Catalyst

Mono atkyl glycerides have bean obtained in good yield by enzyme catalyst from soybean oil. The reaction was carried out in an oil rich microemulslon formula. Best results were obtained with sodium bis(2-ethyl hexyl) sulfo succinate(AOT), isooctane as hydrocarbon component and buffer of pH 7. The enzyme used was a 1,3-specific lipase which leaves the 2-position intact. However, the 2-monoglyceride formed slowly undergoes long chain acyl migration to 1-mono-glyceride. Optimal reaction time at 35℃ reaction temperature was found to be three hour.

[References]

Zlatanos SN, Sagredos AN, Papaglorgiou VP, J. Am. Oil Chem. Soc., 62, 1575 (1985)
Kumar TN, Sastry YSR, Lakshminarayama G, J. Am. Oil Chem. Soc., 66, 153 (1989)
Cook PEE, Showler AJ, J. Am. Chem. Soc., 87, 4594 (1965)
VonFisher W, Wette Seifen Anstrichm., 83, 507 (1981)
Sonntag NOV, J. Am. Oil Chem. Soc., 59, 795A (1982)
Nismo T, Chikano T, Kamimura M, Agric. Biol. Chem., 52, 1203 (1988)
Linfield WM, Barauskas RA, Sivieri L, Serota S, Stevensan RW, J. Am. Oil Chem. Soc., 61, 191 (1984)
Buhler M, Wandrey C, Henkel-Referate, 24, 134 (1988)
Knez Z, Leitgef M, Proceedings of ISF-Jocs World Congress, Tokyop 281 (1988)
Sonnet PE, J. Am. Oil Chem. Soc., 65, 900 (1990)
Wiseman A, "Handbook of Enzyme Biotechnology," 2nd Edn., Ellis Horwood Limi ed., Chichxster (1985)
Meiser P, Luisi PL, J. Solid. Phase Biochem., 5, 269 (1980)
Grandi C, Smith RE, Luisi PL, J. Biol. Chem., 256, 837 (1981)
Barbaric S, Luisi PL, J. Am. Chem. Soc., 103, 4239 (1981)
Fletcher PDI, Robinson BH, Freedman RB, Oldfield C, J. Am. Chem. Soc., 181, 2667 (1985)
Han D, Rhee JS, Biotechnol. Bioeng., 28, 1250 (1986)
Han D, Rhee JS, Biotechnol. Lett., 7, 651 (1985)
Holmberg K, Osterberg E, Prog. Colloid Polym. Sci., 74, 150 (1987)
Dordick JS, Enzyme Microb. Technol., 11, 94 (1989)
Mukderjee KD, Biocatalysis, 3, 277 (1990)
Holmberg K, Osterberg E, J. Am. Oil Chem. Soc., 65, 1544 (1988)
Handschumaker E, Linteris L, J. Am. Oil Chem. Soc., 24, 143 (1947)
Pohle WD, Mehlenbacher VC, J. Am. Oil Chem. Soc., 27, 54 (1950)
Smith RE, Luisi PL, Helv. Chim. Acta, 63, 2302 (1980)

[Referenced By]

[1] Zlatanos SN, Sagredos AN, Papaglorgiou VP, J. Am. Oil Chem. Soc., 62, 1575 (1985)

[2] Kumar TN, Sastry YSR, Lakshminarayama G, J. Am. Oil Chem. Soc., 66, 153 (1989)

[3] Cook PEE, Showler AJ, J. Am. Chem. Soc., 87, 4594 (1965)

[4] VonFisher W, Wette Seifen Anstrichm., 83, 507 (1981)

[5] Sonntag NOV, J. Am. Oil Chem. Soc., 59, 795A (1982)

[6] Nismo T, Chikano T, Kamimura M, Agric. Biol. Chem., 52, 1203 (1988)

[7] Linfield WM, Barauskas RA, Sivieri L, Serota S, Stevensan RW, J. Am. Oil Chem. Soc., 61, 191 (1984)

[8] Buhler M, Wandrey C, Henkel-Referate, 24, 134 (1988)

[9] Knez Z, Leitgef M, Proceedings of ISF-Jocs World Congress, Tokyop 281 (1988)

[10] Sonnet PE, J. Am. Oil Chem. Soc., 65, 900 (1990)

[11] Wiseman A, "Handbook of Enzyme Biotechnology," 2nd Edn., Ellis Horwood Limi ed., Chichxster (1985)

[12] Meiser P, Luisi PL, J. Solid. Phase Biochem., 5, 269 (1980)

[13] Grandi C, Smith RE, Luisi PL, J. Biol. Chem., 256, 837 (1981)

[14] Barbaric S, Luisi PL, J. Am. Chem. Soc., 103, 4239 (1981)

[15] Fletcher PDI, Robinson BH, Freedman RB, Oldfield C, J. Am. Chem. Soc., 181, 2667 (1985)

[16] Han D, Rhee JS, Biotechnol. Bioeng., 28, 1250 (1986)

[17] Han D, Rhee JS, Biotechnol. Lett., 7, 651 (1985)

[18] Holmberg K, Osterberg E, Prog. Colloid Polym. Sci., 74, 150 (1987)

[19] Dordick JS, Enzyme Microb. Technol., 11, 94 (1989)

[20] Mukderjee KD, Biocatalysis, 3, 277 (1990)

[21] Holmberg K, Osterberg E, J. Am. Oil Chem. Soc., 65, 1544 (1988)

[22] Handschumaker E, Linteris L, J. Am. Oil Chem. Soc., 24, 143 (1947)

[23] Pohle WD, Mehlenbacher VC, J. Am. Oil Chem. Soc., 27, 54 (1950)

[24] Smith RE, Luisi PL, Helv. Chim. Acta, 63, 2302 (1980)