화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.42, No.2, 379-383, 1997
Volumetric Properties of Carbon-Dioxide Plus Acetone at High-Pressures
The volumetric properties of carbon dioxide + acetone mixtures have been determined at 323, 348, 373, 398, and 423 K at pressures up to 70 MPa using a variable-volume view cell. Densities for pure components and mixtures containing 90, 80, 70, and 50% by mass carbon dioxide are reported as a function of pressure at each temperature. It is shown that this system undergoes a density crossover at high pressures with each composition, a phenomenon previously reported also for mixtures of carbon dioxide + pentane and carbon dioxide + toluene. In the composition range investigated, the excess volume of the mixtures becomes more positive with increasing pressure but more negative with increasing temperature.