화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.135, No.27, 10018-10021, 2013
Self-Assembled Containers Based on Extended Tetrathiafulvalene
Two original self-assembled containers constituted each by six electroactive subunits are described. They are synthesized from a concave tetratopic pi-extended tetrathiafulvalene ligand bearing four pyridyl units and cis-M(dppf)(OTf)(2) (M = Pd or Pt; dppf = 1,1'-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both fully characterized assemblies present an oblate spheroidal cavity that can incorporate one perylene molecule.