화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.44, No.1, 148-151, 1999
Vapor-liquid equilibria for the binary systems tert-butyl alcohol plus toluene, plus isooctane, and plus methylcyclohexane at 101.3 kPa
Vapor-liquid equilibria were measured for binary systems of tert-butyl alcohol with toluene, isooctane, and methylcyclohexane at 101.3 kPa using a recirculating still. Experimental values of the vapor pressure of non-oxygenated pure components have been obtained. The accuracy of experimental measurements was +/-0.01 K in temperature, +/-0.01 kPa in pressure, and +/-0.001 in mole fractions. The results are thermodynamically consistent according to the point-to-point consistency test. The data were correlated with five liquid-phase activity coefficients models (Margules, Van Laar, Wilson, NRTL, UNIQUAC).