Kissinger Equation과 Fractional Life법에 의한 DGEBA/MDA/MN계와 DGEBA/MDA/MN/HQ계의 경화반응 속도론

이재영; 심미자; 김상욱

Journal of the Korean Industrial and Engineering Chemistry, Vol.5, No.4, 731-736, August, 1994

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Kissinger Equation과 Fractional Life법에 의한 DGEBA/MDA/MN계와 DGEBA/MDA/MN/HQ계의 경화반응 속도론

Cure Kinetics of DGEBA/MBA/MN and DGEBA/MDA/MN/HQ Systems by Kissinger Equation and Fractional Life Method

이재영, 심미자, 김상욱

초록

DGEBA/MDA/MN계와 이 계에 촉매로서 hydroquinone(HQ)를 첨가한 계의 경화반응 속도론을 Fractional life법 및 Kissinger equation에 의해 연구함으로써 HQ가 경화반응 속도에 미치는 영향을 연구하였다. 경화반응 온도가 증가함에 따라 반응속도는 증가하였고, 반응차수는 약간의 변화가 있을 뿐 경화온도에 따른 경향성은 없었다. 촉매로 HQ를 첨가한 계가 첨가하지 않은 계보다 반응속도는 크게 증가하였고, 활성화 에너지는 13% 감소하였다. 이는 HQ의 히드록시기가 에폭사이드기, 아민기와 반응하여 전이상태를 형성함으로써 에폭사이드 고리를 쉽고 빠르게 개환시켜 주기 때문이다.

Cure kinetics of DGEBA/MDA/MN system with and without HQ were studied by Fractional life method and Kissinger equation. And the effect of HQ as a catalyst was studied. As cure temperature increased, the reaction rate increased and reaction order was almost constant. The activation energy of the system with HQ was lower about 13% and the reaction rate was higher than that of the system without HQ. It was because hydroxyl group of HQ formed a transition state with epoxide group and amine group and opened the epoxide ring easily and rapidly.

[References]

Prime RB, "Thermal Characterization of Polymeric Materials," E.A. Turi, Academic Press, New York (1982)
Duffy JV, Hui E, Hartmann B, J. Appl. Polym. Sci., 33, 2959 (1987)
Keenan MR, J. Appl. Polym. Sci., 33, 1725 (1987)
Lee SN, Yuo WB, Polym. Eng. Sci., 27, 1317 (1987)
Sabra A, Pascault JP, Seytre G, J. Appl. Polym. Sci., 32, 5147 (1986)
Mones ET, Morgan RT, Polym. Mater. Sci. Eng., 51, 430 (1986)
Tanaka Y, KakiuchH, J. Macromol. Chem., 1, 307 (1966)
Cho SW, Shim MJ, Kim SW, J. Korean Mater. Res., 2, 257 (1992)
Chern CS, Poehlein GW, Polym. Eng. Sci., 27, 788 (1987)
Riccardi CC, Adabbo HE, Williams RJJ, J. Appl. Polym. Sci., 29, 2481 (1984)
Horie K, Hiura H, Sawada M, Mita I, Kambe H, J. Polym. Sci. A: Polym. Chem., 8, 1357 (1970)
Golub MA, Lerner NR, Hsu MS, J. Appl. Polym. Sci., 32, 5215 (1986)
Chapmann NB, Parker RE, J. Chem. Sci., 2, 1925 (1959)
Cho SW, Shim MJ, Kim SW, "Computer Aided Innovation of New Materials II," North-Holland Part 2, 1439 (1993)

[Referenced By]

[1] Prime RB, "Thermal Characterization of Polymeric Materials," E.A. Turi, Academic Press, New York (1982)

[2] Duffy JV, Hui E, Hartmann B, J. Appl. Polym. Sci., 33, 2959 (1987)

[3] Keenan MR, J. Appl. Polym. Sci., 33, 1725 (1987)

[4] Lee SN, Yuo WB, Polym. Eng. Sci., 27, 1317 (1987)

[5] Sabra A, Pascault JP, Seytre G, J. Appl. Polym. Sci., 32, 5147 (1986)

[6] Mones ET, Morgan RT, Polym. Mater. Sci. Eng., 51, 430 (1986)

[7] Tanaka Y, KakiuchH, J. Macromol. Chem., 1, 307 (1966)

[8] Cho SW, Shim MJ, Kim SW, J. Korean Mater. Res., 2, 257 (1992)

[9] Chern CS, Poehlein GW, Polym. Eng. Sci., 27, 788 (1987)

[10] Riccardi CC, Adabbo HE, Williams RJJ, J. Appl. Polym. Sci., 29, 2481 (1984)

[11] Horie K, Hiura H, Sawada M, Mita I, Kambe H, J. Polym. Sci. A: Polym. Chem., 8, 1357 (1970)

[12] Golub MA, Lerner NR, Hsu MS, J. Appl. Polym. Sci., 32, 5215 (1986)

[13] Chapmann NB, Parker RE, J. Chem. Sci., 2, 1925 (1959)

[14] Cho SW, Shim MJ, Kim SW, "Computer Aided Innovation of New Materials II," North-Holland Part 2, 1439 (1993)