폴리이미드의 제조와 성질에 관한 연구 - IV. 6FDA계 폴리이미드

이동호; 김승환; 유태욱; 구승영

Journal of the Korean Industrial and Engineering Chemistry, Vol.5, No.5, 756-763, October, 1994

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폴리이미드의 제조와 성질에 관한 연구 - IV. 6FDA계 폴리이미드

Studies on Synthesis and Properties of Polyimides : IV. 6FDA-Polyimides

이동호, 김승환, 유태욱, 구승영

초록

2,2-Bis-(3,4-dicarboxyphenyl)hexafluoropropane dianhydride(6FDA), 2,2-bis-[4-(4-aminophenoxy)phenyl]hexafluoropropane 및 4,4-diaminodiphenyl ether 등을 이용하여 단독폴리아믹산, 공폴리아믹산 및 폴리아믹산의 블렌드를 만들고, 열이미드화로 각각의 폴리이미드를 제조하여 구조와 성질을 조사하였다. 그 결과로 열이미드화 동안에 폴리아믹산 간의 교환반응이 일어난다는 것을 알았다. 그리고 공중합이나 폴리아믹산의 블렌드 방법으로 폴리이미드의 분자복합체를 얻을 수 있었다.

Using 2,2-Bis-(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, 2,2-bis-[4-(4-aminophenoxy)phenyl] hexafluoropropane and 4,4-diaminodiphenyl ether, the homopolyamic acids, copolyamic acids and blend of homopolyamic acids were prepared and converted to polyimide(PI)s by thermal imidization. In results, it has been found that a exchange reaction of polyamic acids can be occurred during thermal imidization. With measurement of mechanical properties, it was suggested that PI/PI molecular composite can be obtained by copolymerization or physical blending of homopolyamic acids.

[References]

Lee DH, Polym.(Korea), 11(3), 206 (1987)
Mittal KL, "Polyimide," 5, Plenum Press, New York (1984)
Lee DH, Son IH, Park LS, Koo SY, Polym.(Korea), 13(6), 488 (1989)
Husk GR, Cassidy PE, Gebert KL, Macromolecules, 21, 1234 (1988)
Avadhani CV, Wadgaonkar PP, Vernekar SP, J. Polym. Sci. A: Polym. Chem., 28, 1681 (1990)
Omote T, Koseki K, Yamaoka T, J. Polym. Sci. Polym. Symp., 28, 59 (1990)
Walker CC, J. Polym. Sci. A: Polym. Chem., 26, 1649 (1988)
Breckner MS, Feger C, J. Polym. Sci. A: Polym. Chem., 25, 2479 (1987)
Helminiak TE, Benner CL, Arnold FE, Husman GE, U.S. Patent, 4,207,407 (1980)
Oishi Y, Itoya K, Kakimoto M, Imai Y, Polym. J., 21, 771 (1989)
Yokota R, Horiuchi R, Kochi M, Soma H, Mita I, J. Polym. Sci. Polym. Symp., 26, 215 (1988)
Navarre M, "Polyimide," ed. K.L. Mittal, 1, 429, Plenum Press, New York (1984)
Rebak JF, "Experimental Method in Polymer Chemistry," 221, John Wiley, New York (1984)
Pryde CA, J. Polym. Sci. A: Polym. Chem., 27, 711 (1989)
Patel PS, Sbah PP, Patel SR, J. Macromol. Sci.-Chem., 24, 623 (1987)
Sroog CE, Prog. Polym. Sci., 16, 667 (1991)
Clair TL, "Polyimides," eds. D. Wilson, H.D. Stenzenberger, and P.MN. Hergenrother, 69, Chapman and Hall, New York (1990)

[Referenced By]

[1] Lee DH, Polym.(Korea), 11(3), 206 (1987)

[2] Mittal KL, "Polyimide," 5, Plenum Press, New York (1984)

[3] Lee DH, Son IH, Park LS, Koo SY, Polym.(Korea), 13(6), 488 (1989)

[4] Husk GR, Cassidy PE, Gebert KL, Macromolecules, 21, 1234 (1988)

[5] Avadhani CV, Wadgaonkar PP, Vernekar SP, J. Polym. Sci. A: Polym. Chem., 28, 1681 (1990)

[6] Omote T, Koseki K, Yamaoka T, J. Polym. Sci. Polym. Symp., 28, 59 (1990)

[7] Walker CC, J. Polym. Sci. A: Polym. Chem., 26, 1649 (1988)

[8] Breckner MS, Feger C, J. Polym. Sci. A: Polym. Chem., 25, 2479 (1987)

[9] Helminiak TE, Benner CL, Arnold FE, Husman GE, U.S. Patent, 4,207,407 (1980)

[10] Oishi Y, Itoya K, Kakimoto M, Imai Y, Polym. J., 21, 771 (1989)

[11] Yokota R, Horiuchi R, Kochi M, Soma H, Mita I, J. Polym. Sci. Polym. Symp., 26, 215 (1988)

[12] Navarre M, "Polyimide," ed. K.L. Mittal, 1, 429, Plenum Press, New York (1984)

[13] Rebak JF, "Experimental Method in Polymer Chemistry," 221, John Wiley, New York (1984)

[14] Pryde CA, J. Polym. Sci. A: Polym. Chem., 27, 711 (1989)

[15] Patel PS, Sbah PP, Patel SR, J. Macromol. Sci.-Chem., 24, 623 (1987)

[16] Sroog CE, Prog. Polym. Sci., 16, 667 (1991)

[17] Clair TL, "Polyimides," eds. D. Wilson, H.D. Stenzenberger, and P.MN. Hergenrother, 69, Chapman and Hall, New York (1990)