화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.30, No.11, 1973-1984, November, 2013
DOI10.1007/s11814-013-0193-6  Export Citation
Catalytic applications of immobilized ionic liquids for synthesis of cyclic carbonates from carbon dioxide and epoxides
Dong-Woo Kim, Roshith Roshan, Jose Tharun, Amal Cherian, and Dae-Won Park†
  • School of Chemical and Biomolecular Engineering, Pusan National University, Busan 609-735, Korea
E-mail:
The catalytic applicability of ionic liquids immobilized on various support materials such as silica, polystyrene and biopolymers in the cycloaddition of carbon dioxide with epoxides is reviewed in this work. Comparisons of the catalytic efficiency of these various catalysts have been done from the aspect of turnover number and reusability. The studies revealed that ionic liquids or support materials possessing hydrogen bonding capable groups exhibited enhanced catalytic activity towards cyclic carbonate synthesis. Moreover, the increased quest towards environmentally benign materials has renewed the search for biocompatible materials as support for ionic liquids.
Keywords:Ionic Liquids;Carbon Dioxide;Epoxides;Cyclic Carbonates;Immobilization;Silica;Polystyrene;Biopolymer
  1. Aresta M, Dibenedetto A, Dalton Trans., 28, 2975 (2007)
  2. North M, Pasquale R, Young C, Green Chem., 12, 1514 (2010)
  3. Inoue S, Koinuma H Tsuruta T, J. Polym. Sci., Part B: Polym. Lett., 7, 287 (1969)
  4. Sakakura T, Choi JC, Yasuda H, Chem. Rev., 107(6), 2365 (2007)
  5. Mikkelsen M, Jørgensen M, Krebs FC, Energy Environ. Sci., 3, 43 (2010)
  6. Peters M, Kohler B, Kuckshinrichs W, Leitner W, Markewitz P, Muller TE, ChemSusChem., 4, 1216 (2011)
  7. Gu Y, Li G, Adv. Synth. Catal., 351, 817 (2009)
  8. Weldon T, Coord.Chem. Rev., 248, 2459 (2004)
  9. Chauvin Y, Mussmann L, Olivier H, Angew. Chem. Int. Ed.Eng., 34, 2698 (1995)
  10. Geldbach TJ, Dyson PJ, Metal Catalysed Reactions in Ionic Liquids., Springer (2005)
  11. Wang JQ, Kong DL, Chen JY, Cai F, He LN, J. Mol. Catal. A-Chem., 249(1-2), 143 (2006)
  12. Wang JQ, Yue XD, Cai F, He LN, Catal. Commun., 8, 167 (2006)
  13. Takahashi T, Watahiki T, Kitazume S, Yasuda H, Sakakura T, Chem. Commun., 1664 (2006)
  14. Lee MK, Shim HL, Dharman MM, Kim KH, Park SW, Park DW, Korean J. Chem. Eng., 25(5), 104 (2008)
  15. Udayakumar S, Park SW, Park DW, Choi BS, Catal. Commun., 9, 1635 (2008)
  16. Udayakumar S, Lee MK, Shim HL, Park SW, Park DW, Catal. Commun., 10, 659 (2009)
  17. Shim HL, Udayakumar S, Yu JI, Kim I, Park DW, Catal. Today, 148(3-4), 350 (2009)
  18. Udayakumar S, Raman V, Shim HL, Park DW, Appl. Catal. A: Gen., 368(1-2), 97 (2009)
  19. Han L, Park SW, Park DW, Energy Environ. Sci., 2, 1286 (2009)
  20. Motokura K, Itagaki S, Iwasawa Y, Miyaji A, Baba T, Green Chem., 11, 1876 (2009)
  21. Paddock RL, Hiyama Y, McKay JM, Nguyen SBT, Tetrahedron Lett., 45, 2023 (2004)
  22. Zhang X, Wang D, Zhao N, Al-Arifi ASN, Aouak T, Othaman ZAA, Wei W, Sun Y, Catal. Commun., 11, 43 (2009)
  23. Dharman MM, Choi HJ, Kim DW, Park DW, Catal. Today, 164(1), 544 (2011)
  24. Han L, Park MS, Choi SJ, Kim YJ, Lee SM, Park DW, Catal. Lett., 142(2), 259 (2012)
  25. Han L, Choi HJ, Choi SJ, Liu B, Park DW, Green Chem., 13, 1023 (2011)
  26. Kim MI, Kim DK, Bineesh KV, Kim DW, Selvaraj M, Park DW, Catal. Today., 200, 24 (2013)
  27. Lu J, Toy PH, Chem. Rev., 109(2), 815 (2009)
  28. Chen J, Yang G, Zhang H, Chen Z, React. Funct. Polym., 66(12), 1434 (2006)
  29. Nishikubo T, Kameyama A, Yamashita J, Tomoi M, Fukuda W, J. Polym. Sci., A: Polym. Chem., 31, 939 (1993)
  30. Park JY, Kim JJ, Kim KH, Moon JY, Park DW, React. Kinet. Catal. Lett., 74(1), 29 (2001)
  31. Xie Y, Zhang Z, Jiang T, He J, Han B, Wu T, Ding K, Angew.Chem. Int. Ed., 46, 7255 (2007)
  32. Sun J, Cheng WG, Fan W, Wang YH, Meng ZY, Zhang SJ, Catal. Today, 148(3-4), 361 (2009)
  33. Dai WL, Chen L, Yin SF, Li WH, Zhang YY, Luo SL, Au CT, Catal. Lett., 137(1-2), 74 (2010)
  34. Liang S, Liu H, Jiang T, Song J, Yang G, Han B, Chem. Commun., 47, 213 (2011)
  35. Watile RA, Deshmukh KM, Dhake KP, Bhanage BM, Catal. Sci. Technol., 2, 1051 (2012)
  36. Han L, Choi HJ, Kim DK, Park SW, Liu BY, Park DW, J. Mol. Catal. A-Chem., 338(1-2), 58 (2011)
  37. Zhang YY, Yin SF, Luo SL, Au CT, Ind. Eng. Chem. Res., 51(10), 3951 (2012)
  38. Zhao Y, Tian HS, Qi XH, Han ZN, Zhuang YY, He LN, J. Mol. Catal. A-Chem., 271(1-2), 284 (2007)
  39. Sun J, Wang J, Cheng W, Zhang J, Li X, Zhang S, She Y, Green Chem., 14, 656 (2012)
  40. Roshan KR, Mathai G, Kim J, Tharun J, Park GA, Green Chem., 14, 2933 (2012)
  41. Tharun J, Hwang Y, Roshan R, Ahn S, Kathalikkattil AC, Park DW, Catal. Sci. Technol., 2, 1674 (2012)
  42. Tharun J, Kim DW, Roshan R, Hwang Y, Park DW, Catal.Commun., 31, 62 (2013)