화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.30, No.11, 2059-2067, November, 2013
DOI10.1007/s11814-013-0147-z  Export Citation
Preparation and characterization of poly(dimethylsiloxane)-polytetrafluoroethylene (PDMS-PTFE) composite membrane for pervaporation of chloroform from aqueous solution
De Sun1, 2, Bing-Bing Li2, and Zhen-Liang Xu1, †
  • 1State Key Laboratory of Chemical Engineering, Membrane Science and Engineering R&D Lab., Chemical Engineering Research Center, East China University of Science and Technology (ECUST), 130 Meilong Road, Shanghai 200237, China
  • 2Department of Chemical Engineering, Changchun University of Technology, 2055 Yanan Street, Changchun 130012, P. R. China
E-mail:
Hydrophobic polydimethylsiloxane - polytetrafluoroethylene (PDMS-PTFE) flat-sheet membranes for pervaporation (PV) of chloroform from aqueous solution were successfully fabricated by solution casting method. The structures and the performance of the membranes was characterized by X-ray diffraction (XRD), scanning electron microscope combined with energy dispersive X-ray spectroscopy (SEM-EDXS), Fourier transform infrared spectroscopy (FT-IR), thermal gravimetric analysis (TGA) and the tests of contact angle and mechanical properties. The adding of PTFE particles (<4 μm) in the PDMS matrix enhanced the crystallinity, hydrophobicity, mechanical strength and thermal stability of the membranes. The examinations showed that the PTFE filled PDMS membranes exhibited striking advantages in flux and separation factor as compared with unfilled PDMS membranes. All the filled PDMS membranes with different PTFE content showed excellent PV properties for the separation of chloroform from water. When the content of the PTFE additive in PDMS composite membrane was 30 wt%, membrane performance was the best at feed temperature 50 ℃ and permeate-side vacuum 0.101MPa. For the 30% PTFE-PDMS membrane, with the increase of the feed temperature from 30 to 60 oC, the total, water and chloroform fluxes as well as the separation factor increased, the apparent activation energy (ΔEa) of total, chloroform and water were 21.08, 66.65 and 11.49 KJ/mol, respectively with an increase of chloroform concentration in the feed from 50 to 950 ppm, total, water and chloroform fluxes increased but the separation factor decreased.
Keywords:Poly(dimethylsiloxane);Polytetrafluoroethylene;Membranes;Pervaporation
  1. Luo D, Corey R, Propper R, Collins J, Komorniczak A, Davis M, Berger N, Lum S, Environ. Sci. Policy., 14, 585 (2011)
  2. Preis S, Klauson D, Gregor A, J. Environ. Manage., 114, 125 (2013)
  3. Lee SC, Guo H, Lam SMJ, Lau SLA, Environ. Res., 94, 47 (2004)
  4. Quijano G, Couvert A, Amrane A, Darracq G, Couriol C, Le Cloirec P, Paquin L, Carrie D, Chem. Eng. Sci., 66(12), 2707 (2011)
  5. Templin MV, Jamison KC, Wolf DC, Morgan KT, Butterworth BE, Cancer. Lett., 104, 71 (1996)
  6. Fang C, Behr M, Xie F, Lu S, Doret M, Luo HX, Yang WZ, Aldous K, Ding XX, Gu J, Toxicol. Appl. Pharm., 227, 48 (2008)
  7. Rutkiewicz I, Kujawski W, Namiesnik J, Desalination, 264(1-2), 160 (2010)
  8. Bolto B, Hoang M, Xie ZL, Water Res., 46, 259 (2012)
  9. Jadav GL, Aswal VK, Bhatt H, Chaudhari JC, Singh PS, J. Membr. Sci., 415-416, 624 (2012)
  10. Araki S, Imasaka S, Tanaka S, Miyake Y, J. Membr. Sci., 380(1-2), 41 (2011)
  11. Wei W, Xia SS, Liu GP, Dong XL, Jin WQ, Xu NP, J. Membr. Sci., 375(1-2), 334 (2011)
  12. Le NL, Wang Y, Chung TS, J. Membr. Sci., 379(1-2), 174 (2011)
  13. Shao P, Huang RYM, J. Membr. Sci., 287(2), 162 (2007)
  14. Bennett M, Brisdon BJ, England R, Field RW, J. Membr. Sci., 137(1-2), 63 (1997)
  15. Ohshima T, Kogami Y, Miyata T, Uragami T, J. Membr. Sci., 260(1-2), 156 (2005)
  16. Uragami T, Yamada H, Miyata T, J. Membr. Sci., 187(1-2), 255 (2001)
  17. Lue SJ, Yang TH, Chang KS, Tung KL, J. Membr. Sci., 415-416, 635 (2012)
  18. Lau WW, Finlayson J, Dickson JM, Jiang JX, Brook MA, J. Membr. Sci., 134(2), 209 (1997)
  19. Shirazi Y, Ghadimi A, Mohammadi T, J. Appl. Polym. Sci., 124(4), 2871 (2012)
  20. Liu XL, Li YS, Liu Y, Zhu GQ, Liu J, Yang WS, J. Membr. Sci., 369(1-2), 228 (2011)
  21. Li B, Yu SN, Jiang ZY, Liu WP, Cao RJ, Wu H, J. Hazard. Mater., 211, 296 (2012)
  22. Liu GP, Wei W, Jin WQ, Xu NP, Chin. J. Chem. Eng., 20(1), 62 (2012)
  23. Lee HJ, Cho EJ, Kim YG, Choi IS, Bae HJ, Bioresour.Technol., 109, 110 (2012)
  24. Huang YW, Zhang P, Fu JW, Zhou YB, Huang XB, Tang XZ, J. Membr. Sci., 339(1-2), 85 (2009)
  25. Panek D, Konieuny K, Sep. Purif. Technol., 57(3), 507 (2007)
  26. Khayet M, Matsuura T, Desalination, 148(1-3), 31 (2002)
  27. Simone S, Figoli A, Santoro S, Galiano F, Alfadul SM, Al-Harbi OA, Drioli E, Sep. Purif. Technol., 90, 147 (2012)
  28. Yang ZJ, Zhang WY, Li JD, Chen JX, Sep. Purif. Technol., 93, 15 (2012)
  29. Teoh MM, Chung TS, Sep. Purif. Technol., 66(2), 229 (2009)
  30. Li J, Zhang GJ, Ji SL, Wang NX, An W, J. Membr. Sci., 415-416, 745 (2012)
  31. Chao WC, Huang SH, An QF, Liaw DJ, Huang YC, Lee KR, Lai JY, Polymer, 52(11), 2414 (2011)
  32. Ferreto HFR, Lima LPCP, Parra DP, Zaia V, Lugao AB, Nucl. Instrum. Meth. B., 265, 173 (2007)
  33. Li B, Xu D, Jiang ZY, Zhang XF, Liu WP, Dong XA, J. Membr. Sci., 322(2), 293 (2008)
  34. Dhillo RK, Singh S, Kumar R, Nuclear Nucl. Instrum. Meth.B., 268, 2189 (2010)
  35. Sohail Khan M, Franke R, Lehmann D, Heinrich G, Tribol.Int., 42, 890 (2009)
  36. Hong HS, Chen LX, Zhang QW, He F, Mater. Design., 34, 732 (2012)
  37. Zhan X, Lu J, Tan TT, Li JD, Appl. Surf. Sci., 259, 547 (2012)
  38. Zhou HL, Su Y, Chen XR, Yi SL, Wan YH, Sep. Purif. Technol., 75(3), 286 (2010)
  39. Guo RL, Ma XC, Hu CL, Jiang ZY, Polymer, 48(10), 2939 (2007)
  40. Liu GP, Xiangli FJ, Wei W, Liu SN, Jin WQ, Chem. Eng. J., 174(2-3), 495 (2011)
  41. Peng FB, Jiang ZY, Hu CL, Wang YQ, Xu HQ, Liu JQ, Sep. Purif. Technol., 48(3), 229 (2006)
  42. Yi SL, Su Y, Wan YH, J. Membr. Sci., 360(1-2), 341 (2010)
  43. Lue SJ, Chien CF, Mahesh KPO, J. Membr. Sci., 384(1-2), 17 (2011)
  44. Liu L, Jiang ZY, Pan FS, J. Appl. Polym. Sci., 101(1), 90 (2006)
  45. Eddaoudi M, Li HL, Yaghi OM, J. Am. Chem. Soc., 122(7), 1391 (2000)