화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.6, 2026-2033, November, 2013
DOI10.1016/j.jiec.2013.03.018  Export Citation
Modification of clinoptilolite nano-particles with hexadecylpyridynium bromide surfactant as an active component of Cr(VI) selective electrode
Alireza Nezamzadeh-Ejhieh†, and Mehri Shahanshahi
  • Department of Chemistry, Shahreza Branch, Islamic Azad University, P.O. Box 311-86145, Shahreza, Isfahan, Iran
E-mail:
Clinoptilolite was pretreated by mechanical ball-milling method to obtain nano particles and it was modified by hexadecylpyridynium bromide (HDPBr) surfactant to prepare a surfactant modified zeolite (SMZ) as an effective anion exchanger. The obtained SMZ was used as the active ingredient of a PVC membrane electrode which showed the best Nernstian response toward dichromate in the used conditions. The proposed electrode showed linear response in the concentration range of 1.0 × 10^(-5) to 5.0 × 10^(-2) mol L^(-1) dichromate with a detection limit of 5.0 × 10^(-6) mol L^(-1) at pH = 3-6 and a Nernstian slope of 29.9 0.9 mV per decade of dichromate concentration.
Keywords:Potentiometric sensor;Dichromate-selective electrode;Surfactant-modified zeolite;Hexadecylpyridynium bromide;Nano particles;Clinoptilolite
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