수산기 함유 미세다공성 polystyrene 수지의 합성

정광보; 김학희

Journal of the Korean Industrial and Engineering Chemistry, Vol.6, No.1, 110-114, February, 1995

Export Citation

수산기 함유 미세다공성 polystyrene 수지의 합성

Synthesis of Microporous Polystyrene Resins Containing Hydroxyl Group

정광보, 김학희

초록

2-(vinylbenzyloxy)ethanol 또는 2-(2-vinylbenzyloxyethoxy)ethanol과 styrene, divinylbenzene(2 mol%)과의 현탁 공중합법에 의해 각각 2-Hydroxyethoxymethyl화 또는 2-(2hydroxyethoxy)ethoxymethyl화 미세다공성 polystyrene 수지를 합성하였다. 이들은 여러가지 시약, 리간드, 촉매부를 poly(oxyethylene)쇄에 의해 Polystyrene담체에 고정화시키는 일반적인 담체가 될 것이다.

2-Hydroxyethoxymethylated or 2-(2-hydroxyethoxy)ethoxymethylated microporous polystyrene resins were synthesized by suspension copolymerization of 2-(vinylbenzyloxy) ethanol or 2-(2-vinylbenzyloxyethoxy ) ethanol, respectively, with styrene and divinylbenzene(2 mol-%). These will be a convenient supports to immobilize various reagent, ligand, or catalyst moieties on polystyrene supports by poly(oxyethylene) spacers.

[References]

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Balakrishnan T, Ford WT, J. Org. Chem., 48, 1029 (1983)
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[1] Regen SL, Angew. Chem.-Int. Edit., 18, 421 (1979)

[2] Chiellini E, Solaro R, D'Antone S, Makromol. Chem., 5, 82 (1981)

[3] Regen SL, Nouv. J. Chim., 6, 629 (1982)

[4] Montanari F, Landini D, Rolla F, Fortschr. Chem. Forsch., 101, 147 (1982)

[5] Ford WT, Tomoi M, Fortschr. Hochpolym. Forsch., 55, 49 (1984)

[6] Ford WT, Chemtech., 436 (1984)

[7] Montanari F, Quici S, Anelli PL, Br. Polym. J., 16, 212 (1984)

[8] Montanari H, Montanari F, Quici S, Tundo P, J. Am. Chem. Soc., 101, 3920 (1979)

[9] Regen SL, Bolikal D, Barcelon C, J. Org. Chem., 46, 2511 (1981)

[10] Tomoi M, Ogawa E, Hosokawa Y, Kakiuchi H, J. Polym. Sci. A: Polym. Chem., 20, 3421 (1982)

[11] Anelli PL, Montanari F, Quici S, J. Chem. Soc.-Perkin Trans. 2, 1827 (1983)

[12] Anelli PL, Czech B, Montanari F, Quici S, J. Am. Chem. Soc., 106, 861 (1984)

[13] Tomoi M, Yanai N, Shiiki S, Kakiuchi H, J. Polym. Sci. A: Polym. Chem., 22, 911 (1984)

[14] Tomoi M, Kori N, Kakiuchi H, React. Polym. Ion Exch. Sorbents, 3, 341 (1985)

[15] Tomoi M, Shiiki S, Kakiuchi H, Makromol. Chem., 187, 357 (1986)

[16] Tomoi M, Oda H, Kakiuchi H, Makromol. Chem., 189, 277 (1985)

[17] Ogg CL, Porter WL, Willitis CO, Anal. Chem., 17, 394 (1945)

[18] Tomoi M, Akada Y, Kakiuchi H, Makromol. Chem. Rapid Commun., 3, 537 (1982)

[19] Balakrishnan T, Ford WT, J. Org. Chem., 48, 1029 (1983)

[20] Valter B, Janout V, Hrudkova H, Cefelin P, Lukyanenko NG, Basok SS, Kurigina EY, Polym. Bull., 22, 261 (1989)