가용성 또는 불용성 Polystyrene에 결합된 수산기 함유 Polyetheramine의 합성

정광보; Kohno Y; Tomoi M

Journal of the Korean Industrial and Engineering Chemistry, Vol.6, No.2, 277-282, April, 1995

Export Citation

가용성 또는 불용성 Polystyrene에 결합된 수산기 함유 Polyetheramine의 합성

Synthesis of Hydroxyl-containing Polyetheramines Bound to Soluble or Insoluble Polystyrenes

정광보, Kohno Y, Tomoi M

초록

haloalkyl, tosyloxyalkyl, epoxy기를 함유하는 선형 또는 가교 polystyrene과 bis[2-(2-hydroxethoxy)ethyl]amine(ATEG)과의 반응에 의해 hydroxyl기 함유 polyetheramine 구조의 가용성, 불용성 polystyrene을 합성하였다. 고정화 ATEG의 친수성은 환치환율의 증가에 따라 증가하였고, 친유성은 반대경향을 나타내었다.

Soluble or insoluble polystyrenes with hydroxyl-containing polyetheramine structures were prepared by the reaction of linear or crosslinked polystyrenes containing haloalkyt, tosyloxyalkyl or epoxy groups with bis[2-(2-hydroxyethoxy)ethyl]amine(ATEG). The hydrophilicity of the immobilized ATEG increased with increasing ring substitution and the lipophilicity indicated an opposite tendency.

[References]

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Ford WT, Tomoi M, Adv. Polym. Sci., 55, 49 (1984)
Tomoi M, Ford WT, "Polymeric Phase Transfer Catalysts," in "Syntheses and Separation Using Functional Polymers," Ed. by D.C. Sherrington and P. Hodge, chap. 5, Wiley, Chichester (1988)
Kimura Y, Regen SL, J. Org. Chem., 48, 195 (1989)
Tomoi M, Suzuki T, Kakiuchi H, React. Polym., 10, 27 (1989)
Brdshaw JS, Krakowiak KE, J. Org. Chem., 53, 1808 (1988)
Gokel GW, Garcia BJ, Tetrahedron Lett., 317 (1977)
Tomoi M, Ford WT, J. Am. Chem. Soc., 103, 3821 (1981)
Tomoi M, Ogawa E, Hosokawa Y, Kakiuchi H, J. Polym. Sci. A: Polym. Chem., 20, 3015 (1982)
Chung KB, Tomoi M, J. Polym. Sci. A: Polym. Chem., 30, 1089 (1992)
Tomoi M, Oda H, Kakiuchi H, Makromol. Chem. Rapid Commun., 8, 339 (1987)
Ogg CL, Porter WL, Willits CO, Anal. Chem., 17, 394 (1945)
Tomoi M, Ogawa E, Hosokawa Y, Kakiuchi H, J. Polym. Sci. A: Polym. Chem., 20, 3421 (1982)
Ogawa N, Tomoi M, React. Polym., 13, 55 (1990)
Haradil J, Svec F, Frechet JM, Polymer, 28, 1593 (1987)

[1] Regen SL, Angew. Chem.-Int. Edit., 18, 421 (1979)

[2] Ford WT, Tomoi M, Adv. Polym. Sci., 55, 49 (1984)

[3] Tomoi M, Ford WT, "Polymeric Phase Transfer Catalysts," in "Syntheses and Separation Using Functional Polymers," Ed. by D.C. Sherrington and P. Hodge, chap. 5, Wiley, Chichester (1988)

[4] Kimura Y, Regen SL, J. Org. Chem., 48, 195 (1989)

[5] Tomoi M, Suzuki T, Kakiuchi H, React. Polym., 10, 27 (1989)

[6] Brdshaw JS, Krakowiak KE, J. Org. Chem., 53, 1808 (1988)

[7] Gokel GW, Garcia BJ, Tetrahedron Lett., 317 (1977)

[8] Tomoi M, Ford WT, J. Am. Chem. Soc., 103, 3821 (1981)

[9] Tomoi M, Ogawa E, Hosokawa Y, Kakiuchi H, J. Polym. Sci. A: Polym. Chem., 20, 3015 (1982)

[10] Chung KB, Tomoi M, J. Polym. Sci. A: Polym. Chem., 30, 1089 (1992)

[11] Tomoi M, Oda H, Kakiuchi H, Makromol. Chem. Rapid Commun., 8, 339 (1987)

[12] Ogg CL, Porter WL, Willits CO, Anal. Chem., 17, 394 (1945)

[13] Tomoi M, Ogawa E, Hosokawa Y, Kakiuchi H, J. Polym. Sci. A: Polym. Chem., 20, 3421 (1982)

[14] Ogawa N, Tomoi M, React. Polym., 13, 55 (1990)

[15] Haradil J, Svec F, Frechet JM, Polymer, 28, 1593 (1987)