Journal of Chemical Physics, Vol.100, No.2, 1552-1558, 1994
Solvation Dynamics in Electrolyte-Solutions
A microscopic theory of the dynamics of ion solvation in electrolyte solutions is given. Consistent with the pure solvent case, the theory predicts a very fast and important inertial relaxation at short times. This is followed by oscillations and an extremely slow long-time decay associated with the formation of an equilibrium "ion atmosphere" about the newly charged particle.
Keywords:ORNSTEIN-ZERNIKE EQUATION;MEAN SPHERICAL MODEL;INVARIANT EXPANSION;DIELECTRIC-RELAXATION;SOLVENT;ION;LIQUIDS;SIMULATIONS;SPHERES