화학공학소재연구정보센터
Journal of the Korean Industrial and Engineering Chemistry, Vol.6, No.5, 751-759, October, 1995
배합고무와 강선의 접착에 대한 카본블랙의 영향
The Effects of Carbon Blacks on the Adhesion between Rubber Compounds and Wire
초록
요오드 값과 디부틸프탈레이트 흡수량이 다른 네 종류의 카본블랙이 첨가된 배합고무의 물성과 배합고무와 강선의 접착 성질을 조사하였다. 20∼80phr 범위에서 카본블랙의 첨가량이 많아지면 최대토크, 경도, 모듈러스 등이 커졌으나, 카본블랙 종류의 영향은 크지 않았다. 인장강도와 인열강도도 카본블랙 첨가로 커졌으나, 요오드 값이 큰 카본블랙에서는 첨가량이 80phr 정도로 많아지면 도리어 낮아졌다. 접착세기를 나타내는 TCAT (Tire Cord Adhesion Test) 시편의 pullout force도 카본블랙의 첨가량이 많아질수록 커졌으나, 고무부착정도는 90%로 일정하였다. 배합고무의 100% 모듈러스와 pullout force간의 상관성이 높아서, 카본블랙의 첨가로 인한 접착 증진 효과는 고무의 파괴 저항력이 증진된데 기인하는 것으로 설명되었다.
The effects of carbon blacks mixed to rubber compounds. on various physical properties and adhesion between brass-coated wire and rubber compound were examined in this study. Four types of carbon black with various iodine numbers and dibutylphthalate absorption numbers were used. The maximum torque, hardness, and modulus increased as the mixing amount of carbon black increased in the range of 20∼80 phr. The significance of the types of carbon black to the improvement of strength was not observed. Tensile strength and tear strength were increased by adding carbon black, but decreased at 80 phr of loading level after showing maximum values for the carbon black with relatively larger iodine number. The adhesion strength evaluating by the pullout force of TCAT (Tire Cord Adhesion Test) sample was increased with increasing the amount of carbon black, but the degree of rubber coverage was almost constant as 90%. The plot of 100% modulus of rubber compound versus pullout force showed a linear relationship, indicating that the enhancement of adhesion might be caused by the fatigue resistance of rubber compound improved by carbon black.
  1. Haemers G, Rubber World, Sep., 26 (1980)
  2. vanOoij WJ, Rubber Chem. Technol., 51, 421 (1978)
  3. vanOoij WJ, Rubber Chem. Technol., 54, 227 (1981)
  4. Seo G, Kaang S, Park M, Kim J, Kim M, Moon J, Polym.(Korea), 15(3), 297 (1991)
  5. Seo G, Kaang S, Park M, Jeon G, Kim H, Oh S, Polym.(Korea), 15(4), 383 (1991)
  6. Ayerst RC, Roger ER, Presented at the Rubber Division of ACS Meeting, Cleveland, Ohio, Arpil (1972)
  7. vanOoij WJ, Rubber Chem. Technol., 52, 605 (1979)
  8. Hicks AE, Chiorico VE, Ulmer JD, Rubber Chem. Technol., 45, 26 (1972)
  9. Blow CM, "Rubber Technology and Manufacture," 174, Butterworth & Co., Ltd., London (1977)
  10. Nicholson DW, Livingston DI, Fielding-Russel GS, Gent AN, Tire Sci. Technol., 6, 71 (1978) 
  11. Hmaed GR, "Engineering with Rubber," ed. by A.N. Gent, 21 ~ 22, Hanser, New York (1992)
  12. Gent AN, Rubber Chem. Technol., 56, 1011 (1983)