Novel polyamide 6 (PA6)/fluoroelastomer nanostructured thermoplastic elastomeric blends were developed in the present work. The influence of interaction between the components and morphology on physical properties of the blends was analyzed. Scanning electron microscopy and atomic force microscopy studies, solubility and theoretical analysis of complex modulus clearly indicated that PA6 was the continuous matrix in which fluorocarbon elastomer was present in nanoscale. Low torque ratio (0.34) of rubber/plastic, high mixing speed and long mixing time had an important role in developing the nanostructured morphology of the blend. Tensile strength of the thermoplastic elastomer was about 39.0 MPa which was much higher than that reported earlier and showed significant improvement with increasing PA6 content. Large shifting of the glass transition temperature of the rubber and the plastic phases towards the lower temperature compared to those pristine polymers was also observed. The above properties were explained with the help of interaction between the components and morphology. (C) 2013 Elsevier Ltd. All rights reserved.