Journal of the Korean Industrial and Engineering Chemistry, Vol.6, No.6, 997-1003, December, 1995
금홍석으로부터 융제법에 의한 Postassium Hexatitanate Whisker의 합성
The Synthesis of Potassium Hexatitanate Whisker from Natural Rutile Ore by the Flux Process
초록
생산원가의 절감을 위해서 육티탄산칼륨 섬유는 융제법으로 원료물질을 금홍석, 공업용 K2CO3, 그리고 공업용 K2MoO4를 사용하여 제조하였다. 기 육티탄산칼륨 섬유를 얻기 위한 최적 조건은 반응온도 1050℃, 반응시간 5hrs, K2CO3에 대한 금홍석의 몰비 5.5 그리고 K2CO3와 TiO2 혼합물에 대한 flux의 몰비 4.0이었으며, 적절한 해섬처리 조건은 40배수의 물에 대해 8시간이었다. 이상의 조건으로 합성한 육티탄산칼륨 섬유는 평균 직경 0.5㎛, 평균길이 17㎛였다. 또한 육티탄산칼륨 섬유는 1N HCI에서 60일 후에도 안정하였다.
Fibrous potassium hexatitanate whisker was produced through the flux method using a mixture of the natural rutile ore, industrial K2CO3, and industrial K2MoO4 in an attempts to reduce the fabrication cost. The optimum condition for the synthesis of potassium hexatitanate whisker was the reaction temperature of 1050℃, reaction time of 5 hrs, rutile ore mole ratio to K2CO3 of 5.5, and flux mole ratio to mixture (K2O+ nTiO2) of 4.0. Also the proper water leaching condition for removing of K component was a multiful of 40 for wafter quantity and 8 hrs for leaching lime in boiling water. In this condition, synthisized potassium hexatitanate whisker was a fibrous crystal of 17㎛ of average length and 0.5㎛ of average diameter. Potassium hexatitanate whisker was stabilized after 60 days at 1N HCl.
- Buchner W, Schiebs R, Winter G, Buchel KH, "Industrial Inorganic Chemistry," VCH Pub. N.Y. (1989)
- Noll W, Wilmanns Encyclopedia der Techischer Chemic 4th Ed., 8, Verlag Chemiic, Weinheim-Decrfield Beach-Basel (1974)
- Muto F, Nakagome T, Take S, Yogyo-Kyokai-Shi, 86, 443 (1978)
- Ohta N, Fujiki Y, Yogyo-Kyokai-Shi, 89, 134 (1981)
- Shimizu T, Yogyo-Kyokai-Shi, 85, 567 (1977)
- Fujiki Y, Yogyo-Kyokai-Shi, 91, 189 (1983)
- Shimizu T, Yogyo-Kyokai-Shi, 83, 305 (1975)
- Shimizu T, Yogyo-Kyokai-Shi, 86, 339 (1978)
- Fujiki Y, Izumi F, Yogyo-Kyokai-Shi, 85, 155 (1977)
- Saito H, Takusawa N, Yogyo-Kyokai-Shi, 85, 155 (1977)
- Saito H, Takusawa N, Yogyo-Kyokai-Shi, 67, 297 (1975)
- Lee CT, Kim SW, Lee JS, Kim YM, Kwon KT, J. Korean Ind. Eng. Chem., 5(3), 478 (1994)