Journal of Industrial and Engineering Chemistry, Vol.20, No.1, 274-277, January, 2014
Effects of interfacial interactions of solid microparticles on the emulsion containing ionic liquid
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The present work deals with the effects of ionic liquid and solid microparticles on the properties of emulsions. We found that increasing the concentration of ionic liquid 1-butyl 3-methyl imidazolium hexafluorophosphate (BMIM-PF6) resulted into smaller mean droplet size of the dispersed phase. This effect of ionic liquid is more profound at comparatively low concentration of surfactant. Further, the addition of solid microparticles resulted in comparatively increased stability of the emulsions containing BMIM-PF6 which was the consequence of competitive interactions of solid microparticles and ions at the interfaces present in the emulsions.
Keywords:Droplet size distribution;Ionic liquid;Pickering emulsion;Stability of oil-in-water emulsion;Solid particles;Interfacial interaction
- Kawazoe A, Kawaguchi M, Colloids and Surfaces A., 392, 283 (2011)
- Binks BP, Rodrigues JA, Colloids and Surfaces A., 345, 195 (2009)
- Tcholakova S, Lesov I, Golemanov K, Denkov ND, Judat S, Proc. 5th World Congress on Emulsions, Lyon, France, 20101-53.
- Kong L, Beattie JK, Hunter RJ, Colloids and Surfaces B., 27, 11 (2003)
- Tcholakova S, Denkov ND, Ivanov IB, Campbell B, Advances in Colloid and Interface Science., 123-126, 259 (2006)
- Robins MM, Watson AD, Wilde PJ, Current Opinion in Colloid and Interface Science., 7, 419 (2002)
- Jang W, Nikolov A, Wasan DT, Chen K, Campbell B, Ind. Eng. Chem. Res., 44(14), 4855 (2005)
- Onsaard E, Vittayanont M, Srigam S, McClements DJ, Journal of Agricultural and Food Chemistry., 5747 (2005)
- Lad VN, Murthy ZVP, Ind. Eng. Chem. Res., 51(11), 4222 (2012)
- Dickinson E, Evison J, Owusu RK, Food Hydrocolloids., 5, 481 (1991)
- Lad VN, Murthy ZVP, Journal of Dispersion Science and Technology., 34, 78 (2013)
- Sheldon RA, Lau RM, Sorgedrager MJ, van Rantwijk F, Seddon KR, Green Chemistry., 4, 147 (2002)
- Fang D, Jiao CM, Zhang HB, Ji BH, J. Ind. Eng. Chem., 16(2), 233 (2010)
- Yoon SJ, Lee JG, Tajima H, Yamasaki A, Kiyono F, Nakazato T, Tao H, J. Ind. Eng. Chem., 16(3), 350 (2010)
- Chen W, Yin H, Zhang Y, Lu Z, Wang A, Shen Y, Jiang T, Yu L, J. Ind. Eng. Chem., 16(5), 800 (2010)
- Kang ES, Chae DW, Kim B, Kim YG, J. Ind. Eng. Chem., 18(1), 174 (2012)
- Pilli SR, Banerjee T, Mohanty K, J. Ind. Eng. Chem., 18(6), 1983 (2012)
- Hayyan M, Mjalli FS, Hashim MA, AlNashef IM, Mei TX, J. Ind. Eng. Chem., 19(1), 106 (2013)
- Seth D, Setua P, Chakraborty A, Sarkar N, Journal of Chemical Sciences., 119, 105 (2007)
- Gao Y, Li N, Zheng L, Zhao X, Zhang S, Han B, Hou W, Li G, Green Chemistry., 8, 43 (2006)
- Cheng SQ, Fu XG, Liu JH, Zhang JL, Zhang ZF, Wei YL, Han BX, Colloids and Surfaces A., 302, 211 (2007)
- Qiu Z, Texter J, Current Opinion in Colloid and Interface Science., 13, 252 (2008)
- Chen W, Liu X, Liu Y, Bang Y, Kim HI, J. Ind. Eng. Chem., 17(3), 455 (2011)
- Frost DS, Schoepf JJ, Nofen EM, Dai LL, Journal of Colloid and Interface Science., 383, 103 (2012)
- Arzeni C, Martinez K, Zema P, Arias A, Perez OE, Pilosof AMR, Journal of Food Engineering., 108, 463 (2012)
- Bak A, Podgorska W, Chemical Engineering Science., 74, 181 (2012)
- Xin X, Zhang H, Xu G, Tan Y, Zhang J, Lv X, Colloids and Surfaces A., 418, 60 (2013)
- Tcholakova S, Denkov ND, Ivanov IB, Campbell B, Langmuir, 18(23), 8960 (2002)
- Tcholakova S, Denkov ND, Ivanov IB, Marinov R, Bulgarian Journal of Physics., 31, 96 (2004)
- Gao YN, Han SB, Han BX, Li GZ, Shen D, Li ZH, Du JM, Hou WG, Zhang GY, Langmuir, 21(13), 5681 (2005)
- Ma HA, Dai LL, Langmuir, 27(2), 508 (2011)
- Frelichowska J, Bolzinger MA, Chevalier Y, J. Colloid Interface Sci., 351(2), 348 (2010)
- Walker EM, Frost DS, Dai LL, J. Colloid Interface Sci., 363(1), 307 (2011)
- Yang F, Liu SY, Xu J, Lan Q, Wei F, Sun DJ, J. Colloid Interface Sci., 302(1), 159 (2006)
- Murray BS, Durga K, Yusoff A, Stoyanov SD, Food Hydrocolloids., 25, 627 (2011)
- Binks BP, Current Opinion in Colloid and Interface Science., 7, 21 (2002)
- Binks BP, Horozov TS, Colloidal Particles at Liquid Interfaces, Cambridge University Press, Cambridge (2006)
- Kralchevsky PA, Nagayama K, Particles at Fluid Interfaces and Membranes, Elsevier, Amsterdam (2001)
- McGorty R, Fung J, Kaz D, Manoharan VN, Materials Today., 13, 34 (2010)