화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.1, 345-355, January, 2014
DOI10.1016/j.jiec.2013.03.028  Export Citation
Suitable combination of promoter and micellar catalyst for kilo fold rate acceleration on propanol to propionaldehyde conversion in aqueous media
Aniruddha Ghosh, Rumpa Saha, and Bidyut Saha†
  • Homogeneous Catalysis Laboratory, Department of Chemistry, The University of Burdwan, Golapbag, Burdwan, Pin 713 104, WB, India
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Oxidation of propanol by chromic acid produces propionaldehyde under kinetic condition [propa- nol]T≫ [Cr(VI)]T. This oxidation reaction is performed also in presence of micellar catalysts (anionic, cationic and neutral) and hetero-aromatic nitrogen bases promoters (picolinic acid, 2,2'-bipyridine, 1,10-phenanthroline) in aqueous media. The product is confirmed by 2,4-DNP test and 1H NMR spectroscopy. Anionic surfactant sodium dodecyl sulphate (SDS), neutral surfactant triton X-100 (TX-100) accelerated the reaction both in presence and absence of promoters whereas cationic surfactant Ncetyl pyridinium chloride (CPC) inhibited the reaction. Combination of SDS and bipy is found to be the most efficient for this oxidation.
Keywords:Propanol;Propionaldehyde;Chromic acid;Micellar catalyst;Promoter
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