화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.2, 695-704, March, 2014
DOI10.1016/j.jiec.2013.05.035  Export Citation
Incorporated ZnO onto nano clinoptilolite particles as the active centers in the photodegradation of phenylhydrazine
Alireza Nezamzadeh-Ejhieh†, and Fatemeh Khodabakhshi-Chermahini
  • Department of Chemistry, Shahreza Branch, Islamic Azad University, P.O. Box 311-86145, Shahreza, Isfahan, Iran
E-mail:
ZnO was incorporated into nano particles of clinoptiloite by ion exchanging the zeolite in a zinc nitrate aqueous solution followed by calcinations process. All raw and modified samples were characterized by XRD, FT-IR, DRS, TG-DTG, SEM, BET and TEM. The prepared catalyst was used in the photocatalytic degradation of phenylhydrazine (PHZ) and the best experimental parameters were obtained as: 0.25 g L^(-1) of the catalyst, 20 ppm pollutant concentration and pH = 8. The degradation extent was monitored by UV.vis spectroscopy and the results were confirmed by HPLC and the chemical oxygen demand (COD).
Keywords:ZnO;Nano clinoptilolite;Photodegradation;Phenylhydrazine;Heterogeneous catalysis
  1. Moloney SJ, Prough RA, Hodgeson E, Bend JR, Philpot RM, Rev. Biochem. Toxicol., 5 (1983)
  2. Kamath U, Rao G, Kamath SU, Rai L, Indian J. Clinical Biochem., 21(1), 111 (2006)
  3. Vanaclocha FV, Varona AA, Ayala R, Boyano MD, Guillem EB, Int. J. Cancer, 46, 267 (1990)
  4. Karbownik M, Reiter RJ, Garcia JJ, Tan D, Int. J. Biochem. Cell Biol., 32, 1045 (2000)
  5. Ferrali M, Signorini C, Sugherini L, Pompella A, Lodovici M, Caciotti B, Ciccoli L, Comporti M, Biochem. Pharmacol., 53, 1743 (1997)
  6. Nezamzadeh-Ejhieh A, Moazeni N, J. Ind. Eng. Chem., doi:10.1016/j.jiec.2013.01.006. (2013)
  7. Saien J, Soleymani AR, J. Ind. Eng. Chem., 18(5), 1683 (2012)
  8. Charinpanitkul T, Nartpochananon P, Satitpitakun T, Wilcox J, Seto T, Otani Y, J. INd, 18(1), 469 (2012)
  9. Han XG, He HZ, Kuang Q, Zhou X, Zhang XH, Xu T, Xie ZX, Zheng LS, J. Phys. Chem., 113(2), 584 (2009)
  10. Habibi MH, Sheibani R, J. Ind. Eng. Chem., 19(1), 161 (2013)
  11. Lai YL, Meng M, Yu YF, Appl. Catal. B: Environ., 100(3-4), 491 (2010)
  12. Wang J, Mi W, Tian J, Dai J, Wang X, Liu X, Compos. Part B, 45, 758 (2013)
  13. Yu C, Wang Y, Liu Y, Guo C, Hun Y, Mater. Lett., 100, 278 (2013)
  14. Khatamian M, Alaji Z, Desalination, 286, 248 (2012)
  15. Vu TT, del Rı´o L, Valde´ s-Solı´s T, Marba´ n G, J. Hazard. Mater., 246-247, 126 (2013)
  16. Benhebal H, Chaib M, Leonard A, Lambert SD, Crine M, Mater. Sci. Semicond. Process, 15, 264 (2012)
  17. Krishnakumar B, Swaminathan M, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 99, 160 (2012)
  18. Poulios I, Makri D, Prohaska X, Global NEST, 1, 55 (1999)
  19. Mijin D, Savic M, Snezana P, Smijanic A, Glavaski O, Jovanovic M, Petrovic S, Desalination, 249(1), 286 (2009)
  20. Zhu HY, Jiang R, Fu YQ, Guan YJ, Yao J, Xiao L, Zeng GM, Desalination, 286, 41 (2012)
  21. Martinez C, Canle M, Fernandez MI, Santaballa JA, Faria J, Appl. Catal. B: Environ., 102(3-4), 563 (2011)
  22. Nikazar M, Gholivand K, Mahanpoor K, Desalination, 219(1-3), 293 (2008)
  23. Jibril BY, Atta AY, Al-Waheibi YM, Al-Waheibi TK, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.02.023. (2013)
  24. Nezamzadeh-Ejhieh A, Hushmandrad S, Appl. Catal. A: Gen., 388(1-2), 149 (2010)
  25. Wang HJ, Chen XY, J. Hazard. Mater., 186(2-3), 1888 (2011)
  26. Karunakaran C, Dhanalakshmi R, Gomathisankar P, Spectr, 92, 201 (2012)
  27. Ali O, Namane A, Hellal A, J. Ind. Eng. Chem., 19(4), 1384 (2013)
  28. Bayat M, Sohrabi M, Royaee SJ, J. Ind. Eng. Chem., 18(3), 957 (2012)
  29. Zhai W, Sun FQ, Chen W, Pan ZZ, Zhang LH, Li SH, Feng SL, Liao YY, Li WS, Appl. Catal. A: Gen., 454, 59 (2013)
  30. Ayodele OB, Hameed BH, J. Ind. Eng. Chem., 19(3), 966 (2013)
  31. El-Naas MH, Al-Zuhair S, Makhlouf S, J. Ind. Eng. Chem., 16(2), 267 (2010)
  32. Zhang Q, Cheng X, Zheng C, Feng X, Qiu G, Tan W, Liu F, J. Environ. Sci., 23(11), 1904 (2011)
  33. Faria PCC, Orfao JJM, Pereira MFR, Water Res., 38, 2043 (2004)
  34. American Public Health Association, Standard Methods for the Examination of Water and Wastewater, Washington, DC, 19th ed., 1995. (1995)
  35. Breck DW, Zeolite Molecular Sieves: Structure, Chemistry and Uses, John Wiley& Sons, New York, 1974. (1974)
  36. Bauermann LP, Bill J, Aldinger F, J. Phys. Chem. B, 110(11), 5182 (2006)
  37. Li X, Lva K, Deng K, Tang J, Su R, Sun J, Chen L, Mater. Sci. Eng. B, 158, 40 (2009)
  38. Treacy MMJ, Higgins JB, Collection of Simulated XRD Powder Patterns for Zeolites, 4th revised ed., Elsevier, Amsterdam, 2001. (2001)
  39. Doula MK, Chemosphere, 67, 731 (2007)
  40. Charkhi A, Kazemian H, Kazemeini M, Powder Technol., 203(2), 389 (2010)
  41. Yasyerli S, Ar I, Dogu G, Dogu T, Chem. Eng. Process., 41(9), 785 (2002)
  42. Iznaga IR, Gomez A, Fuentes RG, Aguilar BA, Serrano-no-Ballan J, Microporous Mesoporous Mater., 53, 71 (2002)
  43. Iznaga IR, Petranovskii V, Fuentes GR, Mendoza C, Aguilar AB, J. Colloid Interface Sci., 316(2), 877 (2007)
  44. Tayade RJ, Kulkarni RG, Jasra RV, Ind. Eng. Chem. Res., 45(3), 922 (2006)
  45. Wang C, Xu BQ, Wang X, Zhao J, J. Solid State Chem., 178, 3500 (2005)
  46. Nezamzadeh-Ejhieh A, Moeinirad S, Desalination, 273(2-3), 248 (2011)
  47. Abdolmaleki A, Mallakpour S, Borandeh S, Appl. Surf. Sci., 257(15), 6725 (2011)
  48. Liang ZH, Zhu YJ, Cheng GF, Huang YH, J. Mater. Sci., 42(2), 477 (2007)
  49. Xu JC, Shi YL, Huang JE, Wang B, Li HL, J. Mol. Catal. A-Chem., 219(2), 351 (2004)
  50. Ejhieh AN, Shahriari E, International Journal of Photoenergy (2011) 10, Article ID 518153. (2011)
  51. Ejhieh AN, Khorsandi M, Iran. J. Catal., 1(2), 99 (2011)
  52. Ejhieh AN, Banan Z, Iran. J. Catal., 2(2), 77 (2012)
  53. Nezamzadeh-Ejhieh A, Amiri M, Powder Technol., 235, 279 (2013)
  54. Ejhieh AN, Shirvani K, J. Chem., 11 (2013)
  55. Ejhieh AN, Ghahfarokhi ZS, J. Chem., 11 (2013)
  56. Bansal P, Sud D, Desalination, 267(2-3), 244 (2011)
  57. Gandhi VG, Mishra MK, Rao MS, Kumar A, Joshi PA, Shah DO, J. Ind. Eng. Chem., 17(2), 331 (2011)
  58. Daneshvar N, Salari D, Khataee AR, J. Photochem. Photobiol. A-Chem., 162, 317 (2004)
  59. Sobana N, Swaminathan M, Sep. Purif. Technol., 56(1), 101 (2007)
  60. Schrank SG, Santos JND, Souza DS, Souza EES, J. Photochem. Photobiol. A-Chem., 186, 125 (2007)
  61. Fernandez J, Kiwi J, Lizama C, Freer J, Baeza J, Mansilla HD, J. Photochem. Photobiol. A-Chem., 151, 2013 (2002)
  62. Ahmed S, Rasul MG, Martens WN, Brown R, Hashib MA, Water Air Soil Pollut., 215, 3 (2011)
  63. Byrappa K, Subramany AK, Ananda S, Rai KML, Dinesh R, Yoshimura M, Bull. Mat. Sci., 29, 433 (2006)
  64. Beltran FJ, Gonzalez M, Gonzalez JF, Water Res., 31, 2405 (1997)
  65. Comparelli R, Fanizza E, Curri ML, Cozzi PD, Mascolo G, Agostiano A, Appl. Catal. B: Environ., 60(1-2), 1 (2005)
  66. Natarajan TS, Thomas M, Natarajan K, Bajaj HC, Tayade RJ, Chem. Eng. J., 169(1-3), 126 (2011)
  67. Lu CS, Wu YT, Mai FD, Chung WS, Wu CW, Lin WY, Chen CC, J. Mol. Catal. A-Chem., 310(1-2), 159 (2009)
  68. Neelavann MG, Revathi M, Basha CA, J. Hazard. Mater., 149(2), 371 (2007)
  69. Katsumata H, Matsuba K, Kaneco S, Suzuki T, Ohta K, Yobiko Y, J. Photochem. Photobiol. A-Chem., 170, 239 (2004)
  70. Klare M, Scheen J, Vogelsang K, Jacobs H, Broekaert JAC, Chemosphere, 41, 353 (2000)
  71. Malato S, Blanco J, Richter C, Fernandez P, Maldonado MI, Sol. Energy Mater. Sol. Cells, 64, 1 (2000)
  72. Tasseroul L, Pirard SL, Lambert SD, Paez CA, Poelman D, Pirard JP, Heinrichs B, Chem. Eng. J., 191, 441 (2012)
  73. Rao KVS, Subrahmanyam M, Boule P, Appl. Catal. B: Environ., 49(4), 239 (2004)