화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.22, No.3, 279-286, March, 2014
DOI10.1007/s13233-014-2043-8  Export Citation
Preparation, Structure and Properties of Poly(p-phenylene benzobisoxazole) Composite Fibers Reinforced with Graphene
Young Gyu Jeong†, Doo Hyun Baik, Jin Woo Jang1, Byung Gil Min1, and Kwan Han Yoon2
  • Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University, Daejeon, 305-764, Korea
  • 1Department of Materials Design Engineering, Kumoh National Institute of Technology, Gyeongbuk, 730-701, Korea
  • 2Department of Polymer Science and Engineering, Kumoh National Institute of Technology, Gyeongbuk, 730-701, Korea
E-mail:
Graphene-reinforced poly(p-phenylene benzobisoxazole) (PBO) composite fibers were manufactured via dry-jet wet-spinning of PBO/graphene mixtures in poly(phosphoric acid) (PPA), which were reaction products prepared by the in situ polymerization of 4,6-diaminoresorcinol dihydrochloride and terephthaloyl chloride in the presence of PPA solvent and exfoliated graphene sheets. The content of graphene sheets in the as-spun fibers was adjusted to 0.0~2.0 wt%. The molecular structure, crystalline order, and morphology of the as-spun fibers of pristine PBO and PBO/graphene composites were identified using FTIR, X-ray diffraction, and electron/optical microscopy. The thermal stability and tensile mechanical properties of the composite fiber with 0.2 wt% graphene were found to be significantly improved compared to the pristine PBO fiber.
Keywords:poly(p-phenylene benzobisoxazole) (PBO);graphene;composite fiber;dry-jet wet-spinning;thermal stability;mechanical property.
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