Polymer(Korea), Vol.38, No.3, 299-306, May, 2014
폴리락틱산/산화아연 기둥구조의 유기사포나이트 나노복합체의 특성, 구조 및 결정화
Properties, Structure and Crystallization of Poly Lactic Acid/Zinc Oxide Pillared Organic Saponite Nanocomposites
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ZnO pillared saponite was synthesized via a microwave hydrolysis method. To enhance interfacial compatibility between zinc oxide (ZnO) pillared saponite and poly lactic acid (PLA), ZnO pillared organic saponite was prepared by intercalation modification of cety ltrimethy lammonium bromide. Moreover, PLA/ZnO pillared organic saponite nanocomposites were prepared by melting processing. The microstructure analysis of PLA/ZnO pillared organic saponite nanocomposites showed that ZnO pillared organic saponite was exfoliated and homogeneouslydispersed in PLA matrix. The property results showed that ZnO pillared organic saponite improved the mechanical properties and thermal stabilities of PLA/ZnO pillared organic saponite nanocomposites. Differential scanning calorimetry (DSC) demonstrated that ZnO
pillared organic saponite restrained the appearance of cold crystallization, lowered the glass transition temperature and melting temperature of PLA, and improved the crystallinity of PLA. The results demonstrated that ZnO pillared organic saponite had a good interfacial compatibility and heterogeneous nucleation effect in PLA matrix, and also played an active role in accelerating the crystallization process of PLA.
- Barrau S, Vanmansart C, Moreau M, Addad A, Stoclet G, Lefebvre JM, Seguela R, Macromolecules, 44(16), 6496 (2011)
- Zhou Q, Xanthos M, Polym. Degrad. Stabil., 94, 327 (2009)
- Seppala JV, Helminen AO, Korhonen H, Macromol. Biosci., 4, 208 (2004)
- Pillin I, Montrelay N, Bourmaud A, Grohens Y, Polym. Degrad. Stabil., 93, 321 (2008)
- Zhai WT, Ko Y, Zhu WL, Wong AS, Park CB, Int. J. Mol. Sci., 10(12), 5381 (2009)
- Nam JY, Okamoto M, Okamoto H, Nakano M, Usuki A, Matsuda M, Polymer, 47(4), 1340 (2006)
- Jang WY, Hong KH, Cho BH, Jang SH, Lee SI, Kim BS, Shin BY, Polym.(Korea), 32(2), 116 (2008)
- Lee SH, Kim D, Kim JH, Lee DH, Sim SJ, Nam JD, Kye H, Lee Y, Polym.(Korea), 28(6), 519 (2004)
- Lee JR, Chun SW, Kang HJ, Polym.(Korea), 27(4), 285 (2003)
- Grozdanov A, Buzarovska A, Bogoeva-Gaceva G, Nedkov E, J. Polym. Sci. B: Polym. Phys., 43(1), 66 (2005)
- Kolstad JJ, J. Appl. Polym. Sci., 62(7), 1079 (1996)
- Wu DF, Wu L, Wu LF, Xu B, Zhang YS, Zhang M, J. Polym. Sci. B: Polym. Phys., 45(9), 1100 (2007)
- Paul MA, Alexandre M, Degee P, Henrist C, Rulmont A, Dubois P, Polymer, 44(2), 443 (2003)
- Zhen W, Lu C, Li C, Liang M, Appl. Clay Sci., 57, 64 (2012)
- Kitano M, Hamabe T, Maeda S, J. Crystal Growth, 102, 965 (1990)
- Ogata K, Maejima K, Fujita S, Fujita S, J. Cryst. Growth, 248, 25 (2003)
- Fons P, Iwata K, Yamada A, Matsubara K, Niki S, Nakahara K, Tanabe T, Takasu H, Appl. Phys. Lett, 77, 1081 (2000)
- Li J, Zhen W, Acta Polymerica Sinica, 4, 534 (2013)
- Majdan M, Maryuk O, Pikus S, Olszewska E, Kwiatkowski R, Kkrzypek H, J. Mol. Struct., 740, 203 (2005)
- Ray SS, Yamada K, Okamoto M, Fujimoto Y, Ogami A, Ueda K, Polymer, 44(21), 6633 (2003)
- Pluta M, Galeski A, Alexandre M, Paul MA, Dubois P, J. Appl. Polym. Sci., 86(6), 1497 (2002)
- Chang JH, An YU, Sur GS, J. Polym. Sci. B: Polym. Phys., 41(1), 94 (2003)
- Harris AM, Lee EC, J. Appl. Polym. Sci., 107(4), 2246 (2008)
- Park SD, Todo M, Arakawa K, J. Mater. Sci., 39(3), 1113 (2004)
- Song P, Wei ZY, Liang JC, Chen GY, Zhang WX, Polym. Eng. Sci., 52(5), 1058 (2012)
- Mathew AP, Oksman K, Sain M, J. Appl. Polym. Sci., 101(1), 300 (2006)
- Mogyorosi K, Nemeth J, Dekany I, Fendler JH, Prog. Coll. Polym. Sci., 117, 88 (2002)
- Jiang L, Zhang JW, Wolcott MP, Polymer, 48(26), 7632 (2007)
- Garlotta D, J. Polym. Environ., 9, 63 (2001)
- Kristiansen M, Werner M, Tervoort T, Smith P, Blomenhofer M, Schmidt HW, Macromolecules, 36(14), 5150 (2003)
- Ray SS, Okamoto M, Prog. Polym. Sci., 28, 1539 (2003)
- Ogata N, Kawakage S, Ogihara T, J. Appl. Polym. Sci., 66(3), 573 (1997)