화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.3, 759-766, May, 2014
DOI10.1016/j.jiec.2013.06.004  Export Citation
Liquid phase catalytic dehydration of glycerol to acrolein over Brønsted acidic ionic liquid catalysts
Lingqin Shen, Hengbo Yin†, Aili Wang, Xiufeng Lu, Changhua Zhang, Fen Chen, Yuting Wang, and Huijuan Chen
  • Faculty of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
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Liquid phase dehydration of glycerol to acrolein catalyzed by Brønsted acidic ionic liquids (BAILs) using semi-batch reaction technique was investigated. For the BAILs catalysts, the acrolein yields were in an order of [Bmim]H2PO4 > [Bmim]HSO4 > [BPy]HSO4 > [PSPy]HSO4 > [N2224]HSO4 > [PSPy]H2PO4 > [BPy]H2PO4 > [N2224]H2PO4. When [Bmim]H2PO4 and [Bmim]HSO4 were used as the catalysts at 270 ℃ with the molar ratio of catalyst to glycerol of 1:100, the acrolein yields were 57.4% and 50.8%, respectively, at complete conversion of glycerol. The BAILs with [Bmim] cation and moderate acidity favored the formation of acrolein in liquid phase glycerol dehydration.
Keywords:Acrolein;Glycerol;Brønsted acidic ionic liquid;Dehydration
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