Kinetic and thermodynamic studies on the removal of Cu(II) ions from aqueous solutions by adsorption on modified sand

Deepak Gusain; Varsha Srivastava; Yogesh Chandra Sharma

Journal of Industrial and Engineering Chemistry, Vol.20, No.3, 841-847, May, 2014

DOI10.1016/j.jiec.2013.06.014 Export Citation

Kinetic and thermodynamic studies on the removal of Cu(II) ions from aqueous solutions by adsorption on modified sand

Deepak Gusain, Varsha Srivastava, and Yogesh Chandra Sharma^†

Department of Chemistry, Indian Institute of Technology (Banaras Hindu University) Varanasi, Varanasi 221 005, India

E-mail:

Studies on the removal of copper by adsorption on modified sand have been investigated. The adsorbent was characterized by XRD, FTIR and SEM. Removal of Cu was carried out in batch mode. The values of thermodynamic parameters namely △G0, △H0 and △S0 at 25 ℃ were found to be -0.230 kcal^(-1) mol^(-1), +4.73 kcal^(-1) mol^(-1) and +16.646 cal K^(-1) mol^(-1), respectively. The process of removal was governed by pseudo second order rate equation and value of k2 was found to be 0.122 g mg^(-1) min^(-1) at 25 ℃. The resultant data can serve as baseline data for designing treatment plants at industrial scale.

Keywords:Adsorption;Batch adsorption;Copper;Kinetic study;Sand

[References]

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SenthilKumar P, Ramalingam S, Sathyaselvabala V, Kirupha SD, Sivanesan S, Desalination, 266(1-3), 63 (2011)
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Anupam K, Dutta S, Bhattacharjee C, Datta S, Chem. Eng. J., 173(1), 135 (2011)
Yadav S, Srivastava V, Environ. Sci. Pollut. Res., 20, 558 (2013)
Langmuir I, J. Am. Chem. Soc., 40(9), 1361 (1918)
Ngah WSW, Hanafiah MAKM, Biochem. Eng. J., 39, 521 (2008)
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[Referenced By]

[1] Lifset RJ, Eckelman MJ, Harper EM, Hausfather Z, Urbina G, Sci. Total Environ., 417-418, 138 (2012)

[2] Romana DLD, Olivares M, Uauy R, Araya M, J. Trace Elem. Med. Biol., 25, 3 (2011)

[3] Yurkova IL, Arnhold J, Fitzl G, Huster D, Chem. Phys. Lipids, 164, 393 (2011)

[4] Zavitsanos K, Nunes AM, Malandrinos G, Hadjiliadis N, J. Inorg. Biochem., 105, 102 (2011)

[5] Kozlowski H, Janicka-Klos A, Brasun J, Gaggelli E, Valensin D, Valensin G, Coord. Chem. Rev., 253, 2665 (2009)

[6] Donohue J, Fawell JK, Ohanian E, Giddings M, Toft P, Magara Y, Jackson P, Copper in drinking water, WHO press, Geneva, 2004. (2004)

[7] Lazaridis NK, Peleka EN, Karapantsios TD, Matis KA, Hydrometallurgy, 74, 149 (2004)

[8] Csefalvay E, Pauer V, Mizsey P, Desalination, 240(1-3), 132 (2009)

[9] Chang SH, Teng TT, Ismail N, Alkarkhi AFM, J. Hazard. Mater., 190(1-3), 197 (2011)

[10] Bratskaya SY, Pestov AV, Yatluk YG, Avramenkoa VA, Colloids Surf. A: Physicochem. Eng. Asp., 339, 140 (2009)

[11] Janin A, Blais JF, Mercier G, Drogui P, J. Hazard. Mater., 169(1-3), 1099 (2009)

[12] Chou JD, Lin CL, Hsien YL, Wey MY, Chang SH, Environ. Technol., 33, 17 (2012)

[13] Chen G, Fan J, Liuc R, Zeng G, Chen A, Zouab Z, Environ. Technol., 33, 2653 (2012)

[14] Li YH, Liu FQ, Xia B, Du QJ, Zhang P, Wang DC, Wang ZH, Xia YZ, J. Hazard. Mater., 177(1-3), 876 (2010)

[15] Akbal F, Camci S, Environ. Prog. Sustain. Energy, 31, 340 (2011)

[16] Demirbas E, Dizge N, Sulak MT, Kobya M, Chem. Eng. J., 148(2-3), 480 (2009)

[17] Lin J, Zhan Y, Zhu Z, Colloids Surf. A: Physicochem. Eng. Asp., 384, 9 (2011)

[18] Al-Rashdi B, Tizaoui C, Hilal N, Chem. Eng. J., 183, 294 (2012)

[19] Turan NG, Elevli S, Mesci B, Appl. Clay Sci., 52, 392 (2011)

[20] Lu PJ, Hu WW, Chen TS, Chern JM, Bioresour. Technol., 101(4), 1127 (2010)

[21] Wang L, Lin C, Wub F, J. Taiwan Inst. Chem. Eng., 41, 599 (2010)

[22] SenthilKumar P, Ramalingam S, Sathyaselvabala V, Kirupha SD, Sivanesan S, Desalination, 266(1-3), 63 (2011)

[23] Ramakrishna DM, Viraraghavan T, Jin Y, Pract. Periodic. Hazard. Toxic Radioact. Waste Manage., 10, 198 (2006)

[24] Ghosh A, Saha PD, Desalination Water Treat., 49, 218 (2012)

[25] Anupam K, Dutta S, Bhattacharjee C, Datta S, Chem. Eng. J., 173(1), 135 (2011)

[26] Yadav S, Srivastava V, Environ. Sci. Pollut. Res., 20, 558 (2013)

[27] Langmuir I, J. Am. Chem. Soc., 40(9), 1361 (1918)

[28] Ngah WSW, Hanafiah MAKM, Biochem. Eng. J., 39, 521 (2008)

[29] Gandhi RM, Kousalya GN, Meenakshi S, Int. J. Biol. Macromol., 48, 119 (2011)

[30] Ho YS, Water Res., 37, 2323 (2003)

[31] Daneshvar E, Kousha M, Sohrabi MS, Khataee A, Converi A, Chem. Eng. J., 195-196, 297 (2012)

[32] Masue Y, Loeppert RH, Kramer TA, Environ. Sci. Technol., 41(3), 837 (2007)

[33] Kumar YP, King P, Prasad VSRK, J. Hazard. Mater., 137(2), 1211 (2006)

[34] Nagpal UMK, Bankar AV, Pawar NJ, Kapadnis BP, Zinjarde SS, Water Air Soil Pollut., 215, 177 (2010)

[35] Aydına H, Buluta Y, Yerlikaya C, J. Environ. Manage., 87, 37 (2008)