Raspberry derived mesoporous carbon-tubules and fixed-bed adsorption of pharmaceutical drugs

Shashi Prabha Dubey; Amarendra Dhar Dwivedi; Changha Lee; Young-Nam Kwon; Mika Sillanpaa; Lena Q. Mab

Journal of Industrial and Engineering Chemistry, Vol.20, No.3, 1126-1132, May, 2014

DOI10.1016/j.jiec.2013.06.051 Export Citation

Raspberry derived mesoporous carbon-tubules and fixed-bed adsorption of pharmaceutical drugs

Shashi Prabha Dubey^{1, 2, †}, Amarendra Dhar Dwivedi³, Changha Lee^{1, †}, Young-Nam Kwon^{1, †}, Mika Sillanpaa², and Lena Q. Mab^{3, 4}

¹School of Urban and Environmental Engineering, Ulsan National Institute of Science and Technology (UNIST), 100 Banyeon-ri, Eonyang-eup, Ulju-gun, Ulsan, 698-805, Republic of Korea
²Laboratory of Green Chemistry, Lappeenranta University of Technology, Sammonkatu 12 (Innovation Centre for Safety and Material Technology, TUMA), 50130 Mikkeli, Finland
³State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China
⁴Soil and Water Science Department, University of Florida, Gainesville, FL 32611-0290, USA

E-mail:, ,

Novel mesoporous carbon-tubules were prepared from wild plant leaves of Rubus idaeus (Raspberry) and their physicochemical characteristics were analyzed by spectroscopic and potentiometric titration methods. The developed carbon-tubules were applied for the aqueous phase decontamination of three pharmaceutical drugs. Ibuprofen, naproxen and clofibric acid were selected for the study. Batch and fixed-bed studies were performed to investigate the adsorption of selected pharmaceutical drugs. Mathematical modelings were applied to the experimental data in order to estimate the maximum adsorption capacity and evaluate the characteristics of the fixed-bed. Based on finding, the adsorption mechanism was investigated by adsorbate and adsorbent physicochemical characteristics.

Keywords:Carbon-tubules;Fixed-bed;Mesoporous;Octanol-water partition coefficient;Pharmaceutical drugs

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[Referenced By]

[1] Mertxell G, Mira P, Damia B, Anal. Chem., 81, 898 (2009)

[2] Togunde OP, Oakes KD, Servos MR, Pawliszyn J, Environ. Sci. Technol., 46, 5302 (2012)

[3] Ritter SK, Chem. Eng. News, 84, 37 (2006)

[4] WHO, Pharmaceuticals in Drinking-water, WHO/HSE/WSH/11.05, 2011.

[5] Vulliet E, Olive CC, Loustalot MFG, Environ. Chem. Lett., 9, 103 (2011)

[6] Miao XS, Koenig BG, Metcalfe CD, J. Chromatogr. A, 952, 139 (2002)

[7] Wang L, Ying GG, Zhao JL, Yang XB, Chen F, Tao R, Liu S, Zhou LJ, Sci. Total Environ., 408, 3139 (2010)

[8] Kim JW, Jang HS, Kim JG, Ishibashi H, Hirano M, Nasu K, Ochikawa N, Takao Y, Shinohara R, Arizono K, J. Health Sci., 55, 249 (2009)

[9] Nebot C, Gibb SW, Boyd KG, Anal. Chim. Acta, 598, 87 (2007)

[10] Ternes TA, Water Res., 32, 3245 (1998)

[11] Farre ML, Ferrer I, Ginebreda A, Figueras M, Olivella L, Tirapu L, Vilanova M, Barcelo D, J. Chromatogr. A, 938, 187 (2001)

[12] Ollers S, Singer HP, Fassler P, Muller SR, J. Chromatogr. A, 911, 225 (2001)

[13] Andreozzi R, Raffaele M, Nicklas P, Chemosphere, 50, 1319 (2003)

[14] Lauridsen FS, Birkved M, Hansen LP, Holten Lutzhoft HC, Sorensen BH, Chemosphere, 40, 783 (2000)

[15] Ternes TA, Meisenheimer M, Mcdowell D, Sacher F, Brauch HJ, Gulde BH, Preuss G, Wilme U, Seibert NZ, Environ. Sci. Technol., 36, 3855 (2002)

[16] Petrovic M, Eljarrat E, De Alda MJL, Barcelo D, Trends Anal. Chem., 20, 637 (2001)

[17] Ali I, Gupta VK, Nature Protocols, 1, 2661 (2007)

[18] Dwivedi AD, Gopal K, Jain R, Chem. Eng. J., 168(3), 1279 (2011)

[19] Crittenden JC, Sanongraj S, Bulloch JL, Hand DW, Rogers TN, Speth TF, Ulmer M, Environ. Sci. Technol., 33, 2926 (1999)

[20] Liang C, Li Z, Dai S, Angew. Chem.-Int. Edit., 47, 3696 (2008)

[21] Sui Q, Huang J, Liu Y, Chang X, Ji G, Deng S, Xie T, Yu G, J. Environ. Sci., 23, 177 (2011)

[22] Nakagawa K, Namba A, Mukai SR, Tamon H, Ariyadejwanich P, Tanthapanichakoon W, Water Res., 38, 1791 (2004)

[23] Liangliang J, Fengling L, Zhaoyi X, Shourong Z, Dongqiang Z, Environ. Sci. Technol., 44, 3116 (2010)

[24] Dubey SP, Dwivedi AD, Sillanpaa M, Gopal K, Chem. Eng. J., 165(2), 537 (2010)

[25] USDA, ARS, National Genetic Resources Program. Germplasm Resources Information Network . (GRIN), National Germplasm Resources Laboratory, Beltsville, Maryland, 2006 (last updated on 14/01/2006).

[26] Nakada N, Komori K, Suzuki Y, Environ. Sci., 12, 359 (2005)

[27] Alder AC, Bruchet A, Carballa M, Clara M, Joss A, Loffler D, McArdell CS, Miksch K, Omil F, Tuhkanen T, Ternes TA, in: T.A. Ternes, A. Joss (Eds.), Consumption and Occurrence, 15, IWA Publishing, London, 2006. (2006)

[28] Bui TX, Choi H, J. Hazard. Mater., 168(2-3), 602 (2009)

[29] ASTM, Refractories; Carbon and Graphite Products; Activated Carbon, Annual Book of ASTM Standards, 1995 5.01..

[30] Thomas HC, J. Am. Chem. Soc., 66, 1664 (1944)

[31] Yoon Y, Nelson J, Am. Ind. Hygiene Assocation J., 45, 509 (1984)

[32] Lopes CB, Pereira E, Lin Z, Pato P, Otero M, Silva CM, Duarte AC, Rocha J, Microporous Mesoporous Mater., 145, 32 (2011)

[33] Aksu Z, Ferda GF, Process Biochem., 39, 599 (2004)

[34] Geankoplis CJ, Transport Process and Unit Operations, 3rd ed., PTR Prentice Hall, USA, 1993.

[35] Luehrs DC, Rogers TN, Correlation of the limiting partition coefficient of organic solutes between water and activated carbon with the octanol/water partition coefficient, in: Great Lakes Regional American Chemical Society Meeting, Normal, IL, May 20, 1996.

[36] Weber WJ, Physicochemical Processes, Wiley-Interscience, New York, 1972.

[37] Watson DG, Pharmaceutical Analysis: A Textbook for Pharmacy Students and Pharmaceutical Chemists, 2nd ed., Churchill Livingstone, Edinburgh, 1999.

[38] Lorphensri O, Intravijit J, Sabatini DA, Kibbey TCG, Osathaphan K, Saiwan C, Water Res., 40, 1481 (2006)

[39] Fierro V, Fernandez VT, Celzard A, Microporous Mesoporous Mater., 92, 243 (2006)

[40] Stacy M, Pasquale F, Mietek J, J. Am. Chem. Soc., 130, 15210 (2008)

[41] Lopez E, Soto B, Arias M, Nunez A, Rubinos D, Barral MT, Water Res., 32, 1314 (1998)