Leaching kinetics of Chevreul’s salt in hydrochloric acid solutions

Turan Calban; Burak Kaynarca; Soner Kuslu; Sabri Colak

Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 1141-1147, July, 2014

DOI10.1016/j.jiec.2013.07.005 Export Citation

Leaching kinetics of Chevreul’s salt in hydrochloric acid solutions

Turan Calban, Burak Kaynarca, Soner Kuslu^†, and Sabri Colak

Department of Chemical Engineering, Engineering Faculty, Ataturk University, 25240 Erzurum, Turkey

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The aim of this study was to investigate the dissolution kinetics of Chevreul’s salt in hydrochloric acid [HCl] solutions in a mechanical agitation system and to precipitate Chevreul’s salt [Cu2SO3ㆍCuSO3ㆍ2H2O] using ammonium sulfide [(NH4)2SO3] solutions at various concentrations from synthetic aqueous copper(II) sulfate [CuSO4] solutions. Reaction temperature, concentration of HCl, stirring speed and solid/liquid ratio were selected as parameters. The experimental results were successfully correlated by linear regression using Statistica Package Program. Dissolution curves were evaluated in order to test shrinking core models for solid.fluid systems. It was observed that increase in the reaction temperature and decrease in the solid/liquid ratio causes an increase the dissolution rate of Chevreul’s salt. The dissolution extent is highly increased with increase the concentration of HCl solutions in the experimental conditions. The activation energy was found to be as 57 kJ/mol. The leaching of Chevreul’s salt was controlled by diffusion through the ash or product layer.

Keywords:Chevreul’s salt;Hydrochloric acid;Leaching kinetics

[References]

Habashi F, in: Proceedings of the XVIII International Mineral Processing Congress, Sydney, (1993), pp. 1323.1328.
Habashi F, Dugdale R, Metal, 28129 (1974)
Pietsch EHE (Ed.), Gmelin’s Handbook, Aufl. System No. 60, vol. 8, Verlag Chemie, Weinheim, Bergstrasse, 1958, p. 484.
Kierkegaard P, Nyberg B, Acta Chemica Scaninavica, 19, 2189 (1965)
Jackson E, Hydrometallurgical Extraction and Reclamation, Wiley, New York, 1986, pp. 204.238.
Brant P, Fernando Q, J. Inorg. Nuclear Chem., 40, 235 (1978)
Martins CR, Cabral Neto CA, Alves JJF, de Andrade JB, J. Braz. Chem. Soc., 10, 453 (1999)
Cox XB, Linton RW, Miguel AH, de Andrade JB, Atmos. Environ., 20, 1139 (1986)
Conklin MH, Hoffmann MR, Environ. Sci. Technol., 22, 899 (1988)
Silva LA, Matos JR, de Andrade JB, Thermochim. Acta, 360(1), 17 (2000)
Colak S, Calban T, Yesilyurt M, Sergili D, Ekinci Z, Powder Technol., 134(1-2), 65 (2003)
de Andrade JB, da Silva LA, J. Braz. Chem. Soc., 15, 170 (2004)
Innoue M, Grijalva H, Inoue MB, Fernando Q, Inorg. Chim. Acta., 295, 125 (1999)
Parker AJ, Muir DM, Hydrometallurgy, 6, 239 (1981)
Calban T, Colak S, Yesilyurt M, Chem. Eng. Process., 45(3), 168 (2006)
Yesilyurt M, Calban T, Inz. Chemiczna Proces., 28(1), 85 (2007)
Giovannelli G, Natali S, Zortea L, Bozzini B, Corrosion Sci., 57, 104 (2012)
Fischmann AJ, Dixon DG, Miner. Eng., 23(9), 746 (2010)
Montgomery DC, Design and Analysis of Experiments, John Wiley, New York, 1976.
Gulensoy H, Komplexometrinin Esaslari ve Kompleksometrik Titrasyonlar, Fatih Yayınevi, Istanbul, 1984.
Sookg DA, West DW, Holler FJ, Fundamentals of Analytical Chemistry, 7th ed., Saunders WB Co., Holt, Rinehart and Winston, Saunders College Publishing, New York, NY, USA, 1996.
Levenspiel O, Chemical Reaction Engineering, 2nd ed., Wiley, NewYork, 1972.
Habashi F, Kinetics of Metallurgical Processes, Metallurgie Extractive Quebec, Quebec City, Canada, 1999.
Donmez B, Demir F, Lacin O, J. Ind. Eng. Chem., 15(6), 865 (2009)
Kuslu S, Disli FC, Colak S, J. Ind. Eng. Chem., 16(5), 673 (2010)
Guliyev R, Kuslu S, Calban T, Colak S, J. Ind. Eng. Chem., 18(1), 38 (2012)
Guliyev R, Kuslu S, Calban T, Colak S, J. Ind. Eng. Chem., 18(4), 1202 (2012)

[1] Habashi F, in: Proceedings of the XVIII International Mineral Processing Congress, Sydney, (1993), pp. 1323.1328.

[2] Habashi F, Dugdale R, Metal, 28129 (1974)

[3] Pietsch EHE (Ed.), Gmelin’s Handbook, Aufl. System No. 60, vol. 8, Verlag Chemie, Weinheim, Bergstrasse, 1958, p. 484.

[4] Kierkegaard P, Nyberg B, Acta Chemica Scaninavica, 19, 2189 (1965)

[5] Jackson E, Hydrometallurgical Extraction and Reclamation, Wiley, New York, 1986, pp. 204.238.

[6] Brant P, Fernando Q, J. Inorg. Nuclear Chem., 40, 235 (1978)

[7] Martins CR, Cabral Neto CA, Alves JJF, de Andrade JB, J. Braz. Chem. Soc., 10, 453 (1999)

[8] Cox XB, Linton RW, Miguel AH, de Andrade JB, Atmos. Environ., 20, 1139 (1986)

[9] Conklin MH, Hoffmann MR, Environ. Sci. Technol., 22, 899 (1988)

[10] Silva LA, Matos JR, de Andrade JB, Thermochim. Acta, 360(1), 17 (2000)

[11] Colak S, Calban T, Yesilyurt M, Sergili D, Ekinci Z, Powder Technol., 134(1-2), 65 (2003)

[12] de Andrade JB, da Silva LA, J. Braz. Chem. Soc., 15, 170 (2004)

[13] Innoue M, Grijalva H, Inoue MB, Fernando Q, Inorg. Chim. Acta., 295, 125 (1999)

[14] Parker AJ, Muir DM, Hydrometallurgy, 6, 239 (1981)

[15] Calban T, Colak S, Yesilyurt M, Chem. Eng. Process., 45(3), 168 (2006)

[16] Yesilyurt M, Calban T, Inz. Chemiczna Proces., 28(1), 85 (2007)

[17] Giovannelli G, Natali S, Zortea L, Bozzini B, Corrosion Sci., 57, 104 (2012)

[18] Fischmann AJ, Dixon DG, Miner. Eng., 23(9), 746 (2010)

[19] Montgomery DC, Design and Analysis of Experiments, John Wiley, New York, 1976.

[20] Gulensoy H, Komplexometrinin Esaslari ve Kompleksometrik Titrasyonlar, Fatih Yayınevi, Istanbul, 1984.

[21] Sookg DA, West DW, Holler FJ, Fundamentals of Analytical Chemistry, 7th ed., Saunders WB Co., Holt, Rinehart and Winston, Saunders College Publishing, New York, NY, USA, 1996.

[22] Levenspiel O, Chemical Reaction Engineering, 2nd ed., Wiley, NewYork, 1972.

[23] Habashi F, Kinetics of Metallurgical Processes, Metallurgie Extractive Quebec, Quebec City, Canada, 1999.

[24] Donmez B, Demir F, Lacin O, J. Ind. Eng. Chem., 15(6), 865 (2009)

[25] Kuslu S, Disli FC, Colak S, J. Ind. Eng. Chem., 16(5), 673 (2010)

[26] Guliyev R, Kuslu S, Calban T, Colak S, J. Ind. Eng. Chem., 18(1), 38 (2012)

[27] Guliyev R, Kuslu S, Calban T, Colak S, J. Ind. Eng. Chem., 18(4), 1202 (2012)